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brommethylacetat

Names

[ CAS No. ]:
590-97-6

[ Name ]:
brommethylacetat

[Synonym ]:
MFCD00000170
Bromomethanol acetate
Methanol, 1-bromo-, acetate
Methanol, bromo-, acetate
brommethylacetat
EINECS 209-696-2
Bromomethyl acetate
BROMO METHYL ACETATE

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
132.7±23.0 °C at 760 mmHg

[ Molecular Formula ]:
C3H5BrO2

[ Molecular Weight ]:
152.975

[ Flash Point ]:
57.2±0.0 °C

[ Exact Mass ]:
151.947281

[ PSA ]:
26.30000

[ LogP ]:
0.87

[ Vapour Pressure ]:
8.8±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.450

[ Storage condition ]:
Hygroscopic, -20?C Freezer, Under Inert Atmosphere

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 3272 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

Synthetic Route

Articles

O6-alkylguanine-DNA alkyltransferase has opposing effects in modulating the genotoxicity of dibromomethane and bromomethyl acetate.

Chem. Res. Toxicol. 17(6) , 742-52, (2004)

O(6)-Alkylguanine-DNA alkyltransferase (AGT) is a DNA repair protein that removes O(6)-alkylguanine adducts. The interaction of dibromomethane (CH(2)Br(2)) and bromomethyl acetate (BrCH(2)OAc) with AG...

Optically active cyclohexene derivative as a new antisepsis agent: an efficient synthesis of ethyl (6R)-6-[N-(2-chloro-4-fluorophenyl)sulfamoyl]cyclohex-1-ene-1-carboxylate (TAK-242).

Chem. Pharm. Bull. 54(1) , 58-62, (2006)

Two new synthetic methods were established for the efficient synthesis of optically active cyclohexene antisepsis agent, ethyl (6R)-6-[N-(2-chloro-4-fluorophenyl)sulfamoyl]cyclohex-1-ene-1-carboxylate...

A direct preparation of 1, 2-diacetates from aldehydes and ketones promoted by samarium diiodide. Enholm EJ and Satici H.

Tetrahedron Lett. 32(22) , 2433-36, (1991)


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