brommethylacetat
Names
[ CAS No. ]:
590-97-6
[ Name ]:
brommethylacetat
[Synonym ]:
MFCD00000170
Bromomethanol acetate
Methanol, 1-bromo-, acetate
Methanol, bromo-, acetate
brommethylacetat
EINECS 209-696-2
Bromomethyl acetate
BROMO METHYL ACETATE
Chemical & Physical Properties
[ Density]:
1.6±0.1 g/cm3
[ Boiling Point ]:
132.7±23.0 °C at 760 mmHg
[ Molecular Formula ]:
C3H5BrO2
[ Molecular Weight ]:
152.975
[ Flash Point ]:
57.2±0.0 °C
[ Exact Mass ]:
151.947281
[ PSA ]:
26.30000
[ LogP ]:
0.87
[ Vapour Pressure ]:
8.8±0.2 mmHg at 25°C
[ Index of Refraction ]:
1.450
[ Storage condition ]:
Hygroscopic, -20?C Freezer, Under Inert Atmosphere
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
UN 3272 3/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
3.2
Synthetic Route
Articles
Chem. Res. Toxicol. 17(6) , 742-52, (2004)
O(6)-Alkylguanine-DNA alkyltransferase (AGT) is a DNA repair protein that removes O(6)-alkylguanine adducts. The interaction of dibromomethane (CH(2)Br(2)) and bromomethyl acetate (BrCH(2)OAc) with AG...
Optically active cyclohexene derivative as a new antisepsis agent: an efficient synthesis of ethyl (6R)-6-[N-(2-chloro-4-fluorophenyl)sulfamoyl]cyclohex-1-ene-1-carboxylate (TAK-242).Chem. Pharm. Bull. 54(1) , 58-62, (2006)
Two new synthetic methods were established for the efficient synthesis of optically active cyclohexene antisepsis agent, ethyl (6R)-6-[N-(2-chloro-4-fluorophenyl)sulfamoyl]cyclohex-1-ene-1-carboxylate...
A direct preparation of 1, 2-diacetates from aldehydes and ketones promoted by samarium diiodide. Enholm EJ and Satici H.Tetrahedron Lett. 32(22) , 2433-36, (1991)