di-t-butylmethylphosphine

Names

[ CAS No. ]:
6002-40-0

[ Name ]:
di-t-butylmethylphosphine

[Synonym ]:
ditert-butyl(methyl)phosphane
MFCD01634711

Chemical & Physical Properties

[ Density]:
0.824 g/mL at 25ºC(lit.)

[ Boiling Point ]:
58ºC12 mm Hg(lit.)

[ Molecular Formula ]:
C₉H₂₁P

[ Molecular Weight ]:
160.23700

[ Flash Point ]:
60ºC

[ Exact Mass ]:
160.13800

[ PSA ]:
13.59000

[ LogP ]:
3.69510

[ Appearance of Characters ]:
liquid | colorless

[ Storage condition ]:
Flammables area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H250-H314

[ Precautionary Statements ]:
P222-P231-P280-P305 + P351 + P338-P310-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F,C

[ Risk Phrases ]:
17-34

[ Safety Phrases ]:
S16-S26-S45-S36-S37-S39

[ RIDADR ]:
UN 2845 4.2/PG 1

[ WGK Germany ]:
3

[ HS Code ]:
2901100000

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2901100000

[ Summary ]:
2901100000 saturated acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

Articles

Room-temperature Hiyama cross-couplings of arylsilanes with alkyl bromides and iodides.

J. Am. Chem. Soc. 125 , 5616, (2003)

The first method for achieving Hiyama couplings of unactivated alkyl bromides and iodides is reported. The desired carbon-carbon bond formation proceeds under mild conditions (room temperature) with g...