1,2,4-Triacetoxybenzene

Names

[ CAS No. ]:
613-03-6

[ Name ]:
1,2,4-Triacetoxybenzene

[Synonym ]:
MFCD00008700
EINECS 210-327-2
(3,4-diacetyloxyphenyl) acetate

Chemical & Physical Properties

[ Density]:
1.276g/cm3

[ Boiling Point ]:
357ºC

[ Melting Point ]:
98-100 °C(lit.)

[ Molecular Formula ]:
C₁₂H₁₂O₆

[ Molecular Weight ]:
252.22000

[ Exact Mass ]:
252.06300

[ PSA ]:
78.90000

[ LogP ]:
1.46250

[ Index of Refraction ]:
1.533

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DC4800000

CHEMICAL NAME :: 1,2,4-Benzenetriol, triacetate

CAS REGISTRY NUMBER :: 613-03-6

BEILSTEIN REFERENCE NO. :: 2138876

LAST UPDATED :: 199709

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C12-H12-O6

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: RBPMAZ Revue Belge de Pathologie et de Medecine Experimentale. (Brussels, Belgium) V.18-31, 1947-65. For publisher information, see PTEUA6. Volume(issue)/page/year: 22,1,1952

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
DC4800000

[ HS Code ]:
2915390090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2915390090

[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

Articles

Synthesis of echinamines A and B, the first aminated hydroxynaphthazarins produced by the sea urchin Scaphechinus mirabilis and its analogues.

J. Nat. Prod. 69(8) , 1125-9, (2006)

The first total synthesis of two marine aminated hydroxynaphthazarins, echinamines A (3-amino-7-ethyl-2,5,6,8-tetrahydroxy-1,4-naphthoquinone) and B (2-amino-7-ethyl-3,5,6,8-tetrahydroxy-1,4-naphthoqu...