Triethylsilane
Names
[ CAS No. ]:
617-86-7
[ Name ]:
Triethylsilane
[Synonym ]:
triethylsilicon
MFCD00009018
Silane, triethyl-
Triethylsilane
UNII:0F9429873L
Triethylsilyl hydride
EINECS 210-535-3
Chemical & Physical Properties
[ Density]:
0.728 g/mL at 25 °C(lit.)
[ Boiling Point ]:
107.5±0.0 °C at 760 mmHg
[ Melting Point ]:
-157°C
[ Molecular Formula ]:
C6H16Si
[ Molecular Weight ]:
116.277
[ Flash Point ]:
-3.9±0.0 °C
[ Exact Mass ]:
116.102127
[ LogP ]:
3.66
[ Vapour Pressure ]:
31.6±0.1 mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.412(lit.)
[ Storage condition ]:
2-8°C
[ Stability ]:
Stable, but moisture sensitive. Highly flammable. Generates highly flammable gas (hydrogen) in contact with water, acids and bases.
MSDS
Safety Information
[ Symbol ]:
GHS02
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H412
[ Precautionary Statements ]:
P210-P273
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Flammable
[ Risk Phrases ]:
R11;R36/37/38
[ Safety Phrases ]:
S9-S16-S29-S33-S37/39-S26
[ RIDADR ]:
UN 1993 3/PG 2
[ WGK Germany ]:
1
[ Packaging Group ]:
II
[ Hazard Class ]:
3
[ HS Code ]:
29310095
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Angew. Chem. Int. Ed. Engl. 53(52) , 14527-32, (2014)
The synthesis of colloidal nanocrystals (NCs) of lithiated group 14 elements (Z=Si, Ge, and Sn) is reported, which are Li4.4 Si, Li3.75 Si, Li4.4 Ge, and Li4.4 Sn. Lix Z compounds are highly reactive ...
Discovery of XEN907, a spirooxindole blocker of NaV1.7 for the treatment of painBioorg. Med. Chem. Lett. 21 , 3676-3681, (2011)
Starting from the oxindole 2a identified through a high-throughput screening campaign, a series of Na(V)1.7 blockers were developed. Following the elimination of undesirable structural features, preli...
Stereochemical control in the reduction of 2-chromanols.Org. Lett. 8 , 4711, (2006)
[reaction: see text] Reduction of C5-substituted 2-hydroxychromans selectively provides 2,4-cis-chromans using large silane reductants and 2,4-trans-chromans using the smaller silane PhSiH(3). The ste...