Methyl 3-bromobenzoate

Names

[ CAS No. ]:
618-89-3

[ Name ]:
Methyl 3-bromobenzoate

[Synonym ]:
3-methoxycarbonyl-1-bromobenzene
(3-bromophenyl)acetic acid methyl ester
m-bromobenzoic acid methyl ester
Methyl 3-bromobenzoate
Benzoic acid, m-bromo-, methyl ester
MFCD00017777
Benzoic acid,3-bromo-,methyl ester
Methyl-3-brombenzolcarboxylat
Benzoic acid, 3-bromo-, methyl ester
methyl-3-bromobenzoate
Methyl m-bromobenzoate
EINECS 210-569-9
3-MeO2CC6H4Br
3-Bromobenzoic acid,methyl ester

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
244.4±13.0 °C at 760 mmHg

[ Melting Point ]:
31-33 °C(lit.)

[ Molecular Formula ]:
C₈H₇BrO₂

[ Molecular Weight ]:
215.044

[ Flash Point ]:
101.6±19.8 °C

[ Exact Mass ]:
213.962936

[ PSA ]:
26.30000

[ LogP ]:
2.88

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.550

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a molecular source of nanoparticles, and the reactions involved in the catalyst-deactivation processes.

Chemistry 18(10) , 2978-86, (2012)

Dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium [(P{(NC(5)H(10))(C(6)H(11))(2)})(2)PdCl(2)] (1) is a highly active and generally applicable C-C cross-coupling catalyst. Apart from its hig...

Dual catalysis. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis.

Science 345(6195) , 433-6, (2014)

The routine application of C(sp3)-hybridized nucleophiles in cross-coupling reactions remains an unsolved challenge in organic chemistry. The sluggish transmetalation rates observed for the preferred ...

Negishi cross-coupling reaction catalyzed by an aliphatic, phosphine based pincer complex of palladium. biaryl formation via cationic pincer-type Pd^IV intermediates. Gerber R, et al.

Dalton Trans. 40(35) , 8996-9003, (2011)