3-Iodotoluene
Names
[ CAS No. ]:
625-95-6
[ Name ]:
3-Iodotoluene
[Synonym ]:
3-methyliodobenzene
3-iodo-toluene
Toluene,m-iodo-(7CI,8CI)
Toluene,m-iodo
3-Methylphenyl iodide
EINECS 210-918-5
Benzene,1-iodo-3-methyl
3-Iodotoluene
Toluene, m-iodo-
m-Iodotoluene
MFCD00001050
m-Tolyl iodide
Benzene, 1-iodo-3-methyl-
1-Iodo-3-methylbenzene
3-Me-C6H4-I
m-Methyliodobenzene
Chemical & Physical Properties
[ Density]:
1.7±0.1 g/cm3
[ Boiling Point ]:
213.0±0.0 °C at 760 mmHg
[ Melting Point ]:
-27°C
[ Molecular Formula ]:
C7H7I
[ Molecular Weight ]:
218.035
[ Flash Point ]:
82.2±0.0 °C
[ Exact Mass ]:
217.959229
[ LogP ]:
3.71
[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.605
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DA3440000
- CHEMICAL NAME :
- Benzene, 1-iodo-3-methyl-
- CAS REGISTRY NUMBER :
- 625-95-6
- BEILSTEIN REFERENCE NO. :
- 1903634
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C7-H7-I
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2296 mg/kg
- TOXIC EFFECTS :
- Behavioral - convulsions or effect on seizure threshold
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 36(9-10),44,1992
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
UN 2810
[ WGK Germany ]:
2
[ RTECS ]:
DA3440000
[ HS Code ]:
2903999090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2903999090
[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Angew. Chem. Int. Ed. Engl. 50(20) , 4671-4, (2011)
Palladium-catalyzed synthesis of indene derivatives via propargylic carbonates with in situ generated organozinc compounds.
Org. Biomol. Chem. 6(6) , 1040-5, (2008)
The palladium-catalyzed carboannulation and arylation reaction of propargylic carbonates with in situ generated organozinc compounds produced an important new class of indene derivatives. The reaction...
[Information on basics of MAC for m-toluate iodide in the air of work area].Gig. Tr. Prof. Zabol. (9-10) , 44-5, (1992)