1-nitrobutane

Names

[ CAS No. ]:
627-05-4

[ Name ]:
1-nitrobutane

[Synonym ]:
n-butylnitrit
1-nitrobutane
4-nitro-1-butane
EINECS 210-980-3
MFCD00007409
nitrobutane

Chemical & Physical Properties

[ Density]:
0.973 g/mL at 25ºC(lit.)

[ Boiling Point ]:
152-153ºC(lit.)

[ Melting Point ]:
-81ºC(lit.)

[ Molecular Formula ]:
C₄H₉NO₂

[ Molecular Weight ]:
103.12000

[ Flash Point ]:
44ºC

[ Exact Mass ]:
103.06300

[ PSA ]:
45.82000

[ LogP ]:
1.58640

[ Index of Refraction ]:
n20/D 1.410(lit.)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EK5075000

CHEMICAL NAME :: Butane, 1-nitro-

CAS REGISTRY NUMBER :: 627-05-4

BEILSTEIN REFERENCE NO. :: 1743017

LAST UPDATED :: 199612

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C4-H9-N-O2

MOLECULAR WEIGHT :: 103.14

WISWESSER LINE NOTATION :: WN4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - ataxia Lungs, Thorax, or Respiration - respiratory stimulation

REFERENCE :: JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 22,315,1940 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 30 mg/m3 JAN 1993

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Risk Phrases ]:
R10

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
EK5075000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Articles

Photoelectron spectroscopy of 1-nitropropane and 1-nitrobutane anions.

J. Chem. Phys. 136(6) , 064307, (2012)

We present low-energy velocity map photoelectron imaging results for bare and Ar-solvated 1-nitropropane and 1-nitrobutane anions. We report the adiabatic electron affinity of 1-nitropropane as (223 ±...

Hydrothermal reactions of 1-nitrobutane in high-temperature water. Iyer SD, et al.

J. Supercrit. Fluids 9(1) , 26-32, (1996)