Methyl carbazate
Names
[ CAS No. ]:
6294-89-9
[ Name ]:
Methyl carbazate
[Synonym ]:
Carbazic acid methyl ester
EINECS 228-560-3
methyl N-aminocarbamate
Hydrazinecarboxylic acid, methyl ester
MFCD00007594
Methyl hydrazinecarboxylate
Methyl carbazate
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
230.9±0.0 °C at 760 mmHg
[ Melting Point ]:
70-73 °C(lit.)
[ Molecular Formula ]:
C2H6N2O2
[ Molecular Weight ]:
90.081
[ Flash Point ]:
86.1±18.7 °C
[ Exact Mass ]:
90.042931
[ PSA ]:
64.35000
[ LogP ]:
-0.79
[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.435
[ Water Solubility ]:
soluble
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
T:Toxic;Xi:Irritant;
[ Risk Phrases ]:
R23/25;R36/37/38;R48
[ Safety Phrases ]:
S26-S37/39-S45-S38-S36/37/39-S22
[ RIDADR ]:
2811
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1
[ HS Code ]:
2928000090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2928000090
[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%
Articles
J. Med. Chem. 28(11) , 1704-16, (1985)
By using inhibition of histamine release from antigen-challenged, sensitized human basophils as a means of identifying a potentially prophylactic drug for the treatment of asthma, a series of substitu...
Methyl 3-(4-methyl-benzyl-idene)carbazate.Acta Crystallogr. Sect. E Struct. Rep. Online 66(Pt 6) , o1429, (2010)
The title compound, C(10)H(12)N(2)O(2), was prepared by the reaction of methyl carbazate and 4-methyl-benzaldehyde. The dihedral angle between the benzene ring and the carbazate fragment is 20.86 (10)...
Negative results of carcinogenicity bioassay of methyl carbazate in rats: significance for the toxicological evaluation of carbadox.Toxicology 22(3) , 219-21, (1981)
Methyl carbazate, a metabolite of carbadox in the rat, was administered orally to rats for 2 years. The compound was mixed in the diet at concentrations corresponding to dose levels of 0, 2.5, 5 and 1...