(Trimethylsilyl)methyl trifluoromethanesulfonate

Names

[ Name ]:
(Trimethylsilyl)methyl trifluoromethanesulfonate

[Synonym ]:
Methanesulfonic acid, 1,1,1-trifluoro-, (trimethylsilyl)methyl ester
(Trimethylsilyl)methyl trifluoromethanesulfonate
trimethylsilylmethyl trifluoromethanesulfonate
MFCD00009914

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
168.8±0.0 °C at 760 mmHg

[ Melting Point ]:
<0ºC

[ Molecular Formula ]:
C₅H₁₁F₃O₃SSi

[ Molecular Weight ]:
236.285

[ Flash Point ]:
48.3±0.0 °C

[ Exact Mass ]:
236.015030

[ PSA ]:
51.75000

[ LogP ]:
2.51

[ Vapour Pressure ]:
2.1±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.387

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R10;R34

[ Safety Phrases ]:
S26-S28-S36/37/39-S45

[ RIDADR ]:
UN 2920 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

O. Tsuge et al.

Chem. Lett. , 279, (1984)

A. Padwa et al.

J. Org. Chem. 49 , 3314, (1984)

K.K. Wang, K.E. Yang

Tetrahedron Lett. 28 , 1003, (1987)