1-Propynyltributylstannane

Names

[ Name ]:
1-Propynyltributylstannane

[Synonym ]:
(1-propynyl)tri-n-butyltin
tributyl(1-propynyl)stannane
Tributyl(1-propyn-1-yl)stannane
MFCD03265213
propynyltributyltin
Stannane, tributyl-1-propyn-1-yl-
tributyl(1-propynyl)tin
tributyl (1-propyn-1-yl)tin
(1-propynyl)-tri-n-butylstannane
Tributyl(prop-1-yn-1-yl)stannane
TRIBUTYLPROPYNYLSTANNANE

Chemical & Physical Properties

[ Density]:
1.082

[ Boiling Point ]:
316.3±25.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₅H₃₀Sn

[ Molecular Weight ]:
329.109

[ Flash Point ]:
149.1±10.3 °C

[ Exact Mass ]:
330.136963

[ LogP ]:
9.80

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.483(lit.)

[ Storage condition ]:
2~8℃

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H312-H315-H319-H372-H410

[ Precautionary Statements ]:
P273-P280-P301 + P310-P305 + P351 + P338-P314-P501

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;N: Dangerous for the environment;

[ Risk Phrases ]:
21-25-36/38-48/23/25-50/53

[ Safety Phrases ]:
35-36/37/39-45-60-61

[ RIDADR ]:
UN 2788 6.1/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

A new two-step four-component synthesis of highly functionalized cyclohexenols by sequential nickel-catalyzed couplings.

J. Am. Chem. Soc. 124 , 2106-2107, (2002)

A new two-step procedure for the synthesis of cyclohexenols has been developed. A nickel-catalyzed three-component addition of an enal, alkyne, and acetylenic tin affords substituted hept-4-en-6-ynals...