tetramethylhydrazine

Names

[ Name ]:
tetramethylhydrazine

[Synonym ]:
Hydrazine,1,1,2,2-tetramethyl
N,N,N',N'-tetramethylenediamine
N,N,N',N'-tetramethyl-hydrazine
(CH3)2NN(CH3)2
tetramethylenediamine
Tetramethyl-hydrazin
tetramethyl-hydrazine
EINECS 229-119-8

Chemical & Physical Properties

[ Density]:
0.777 g/mL at 20ºC(lit.)

[ Boiling Point ]:
67.1ºC at 760 mmHg

[ Molecular Formula ]:
C₄H₁₂N₂

[ Molecular Weight ]:
88.15150

[ Flash Point ]:
27ºC

[ Exact Mass ]:
88.10000

[ PSA ]:
6.48000

[ LogP ]:
0.02460

[ Index of Refraction ]:
n20/D 1.404

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Risk Phrases ]:
10

[ Safety Phrases ]:
23-24/25

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2928000090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2928000090

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

A free radical mediated cooxidation of tetramethylhydrazine by prostaglandin hydroperoxidase.

Carcinogenesis 4(10) , 1341-3, (1983)

Prostaglandin endoperoxide synthase catalyzed the oxidation of tetramethylhydrazine to the tetramethylhydrazine radical cation, as detected by electron spin resonance spectroscopy. Oxidation of tetram...

Fatty acid stimulated N-demethylation of 1,2-dimethylhydrazine and tetramethylhydrazine by rat colonic mucosa.

Biochem. Pharmacol. 34(17) , 3101-6, (1985)

A fatty acid stimulated, NADPH-independent pathway for the N-demethylation of 1,1-dimethylhydrazine (1,1-DMH) with the generation of HCHO was demonstrated in 10,000 g soluble fractions of colonic muco...

An electron spin resonance study of the novel radical cation produced during the horseradish peroxidase-catalyzed oxidation of tetramethylhydrazine.

Biochem. Biophys. Res. Commun. 105(1) , 217-24, (1982)