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4-aminoheptafluorotoluene

Names

[ CAS No. ]:
651-83-2

[ Name ]:
4-aminoheptafluorotoluene

[Synonym ]:
2,3,5,6-Tetrafluoro-4-(trifluoromethyl)aniline
Benzenamine, 2,3,5,6-tetrafluoro-4-(trifluoromethyl)-
2,3,5,6-Tetrafluor-4-(trifluormethyl)anilin
2,3,5,6-tetrafluoro-4-trifluoromethylaniline
MFCD00091518
4-aminoheptafluorotoluene

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
171.7±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H2F7N

[ Molecular Weight ]:
233.086

[ Flash Point ]:
67.9±18.0 °C

[ Exact Mass ]:
233.007553

[ PSA ]:
26.02000

[ LogP ]:
3.28

[ Vapour Pressure ]:
1.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.413

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2921420090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Pd(II)-catalyzed carbonylation of C(sp3)-H bonds: a new entry to 1,4-dicarbonyl compounds.

J. Am. Chem. Soc. 49th ed., 132 , 17378-17380, (2010)

Pd(II)-catalyzed β-C(sp(3))-H carbonylation of N-arylamides under CO (1 atm) has been achieved. Following amide-directed C(sp(3))-H cleavage and insertion of CO into the resulting [Pd(II)-C(sp(3))] bo...

Pd-catalyzed intermolecular C-H amination with alkylamines.

J. Am. Chem. Soc. 20th ed., 133 , 7652-7655, (2011)

C-H amination of N-aryl benzamides with O-benzoyl hydroxylamines has been achieved with either Pd(II) or Pd(0) catalysts. Furthermore, we demonstrate that secondary amines can be directly used with be...

Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes.

J. Am. Chem. Soc. 49th ed., 133 , 19598-19601, (2011)

Systematic ligand development has led to the identification of novel mono-N-protected amino acid ligands for Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes. A diverse range of organ...


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Related Compounds