4-aminoheptafluorotoluene
Names
[ CAS No. ]:
651-83-2
[ Name ]:
4-aminoheptafluorotoluene
[Synonym ]:
2,3,5,6-Tetrafluoro-4-(trifluoromethyl)aniline
Benzenamine, 2,3,5,6-tetrafluoro-4-(trifluoromethyl)-
2,3,5,6-Tetrafluor-4-(trifluormethyl)anilin
2,3,5,6-tetrafluoro-4-trifluoromethylaniline
MFCD00091518
4-aminoheptafluorotoluene
Chemical & Physical Properties
[ Density]:
1.6±0.1 g/cm3
[ Boiling Point ]:
171.7±40.0 °C at 760 mmHg
[ Molecular Formula ]:
C7H2F7N
[ Molecular Weight ]:
233.086
[ Flash Point ]:
67.9±18.0 °C
[ Exact Mass ]:
233.007553
[ PSA ]:
26.02000
[ LogP ]:
3.28
[ Vapour Pressure ]:
1.4±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.413
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2921420090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2921420090
[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
J. Am. Chem. Soc. 49th ed., 132 , 17378-17380, (2010)
Pd(II)-catalyzed β-C(sp(3))-H carbonylation of N-arylamides under CO (1 atm) has been achieved. Following amide-directed C(sp(3))-H cleavage and insertion of CO into the resulting [Pd(II)-C(sp(3))] bo...
Pd-catalyzed intermolecular C-H amination with alkylamines.J. Am. Chem. Soc. 20th ed., 133 , 7652-7655, (2011)
C-H amination of N-aryl benzamides with O-benzoyl hydroxylamines has been achieved with either Pd(II) or Pd(0) catalysts. Furthermore, we demonstrate that secondary amines can be directly used with be...
Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes.J. Am. Chem. Soc. 49th ed., 133 , 19598-19601, (2011)
Systematic ligand development has led to the identification of novel mono-N-protected amino acid ligands for Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes. A diverse range of organ...