(2R)-2-[(Trityloxy)methyl]oxirane
Names
[ CAS No. ]:
65291-30-7
[ Name ]:
(2R)-2-[(Trityloxy)methyl]oxirane
[Synonym ]:
MFCD00273368
Oxirane, 2-[(triphenylmethoxy)methyl]-, (2R)-
(2R)-2-(trityloxymethyl)oxirane
(2R)-2-[(Trityloxy)methyl]oxirane
Chemical & Physical Properties
[ Density]:
1.1±0.1 g/cm3
[ Boiling Point ]:
438.8±40.0 °C at 760 mmHg
[ Melting Point ]:
99-102 °C(lit.)
[ Molecular Formula ]:
C22H20O2
[ Molecular Weight ]:
316.393
[ Flash Point ]:
164.8±26.9 °C
[ Exact Mass ]:
316.146332
[ PSA ]:
21.76000
[ LogP ]:
6.50
[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C
[ Index of Refraction ]:
1.603
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S37/39-S26
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2910900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2910900090
[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
Articles
Tetrahedron Lett. 35 , 3243, (1994)
Bennett, M.J. et al.
Tetrahedron Lett. 36 , 2207, (1995)
Lin, H.-K. Gelb, M.H.
J. Am. Chem. Soc. 115 , 3932, (1993)