Bis(diethylamino)chlorophosphine

Names

[ CAS No. ]:
685-83-6

[ Name ]:
Bis(diethylamino)chlorophosphine

[Synonym ]:
MFCD00015493
Bisdiethylamino-chloro-phosphine
tetraethyldiamidophosphorous acid chloride
Phosphorodiamidous chloride, tetraethyl-
N,N,N',N'-Tetraethylphosphorodiamidous chloride
tetraethyldiamidophophorous acid chloride
Bdapcd
Phosphorodiamidous chloride, N,N,N',N'-tetraethyl-
Bis(diethylamino)chlorophosphine

Chemical & Physical Properties

[ Density]:
1.002 g/mL at 25 °C(lit.)

[ Boiling Point ]:
235.3±23.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₂₀ClN₂P

[ Molecular Weight ]:
210.685

[ Flash Point ]:
96.1±22.6 °C

[ Exact Mass ]:
210.105255

[ PSA ]:
20.07000

[ LogP ]:
3.52

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.4895(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R14;R34

[ Safety Phrases ]:
S23-S26-S36-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2929909090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2929909090

[ Summary ]:
2929909090 other compounds with other nitrogen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthesis and interactive properties of an oligonucleotide with anthraquinone at the sugar fragment.

Bioconjug. Chem. 1(5) , 319-24, (1990)

The synthesis of a self-complementary oligonucleotide possessing an anthraquinonylmethyl substituent at the designated sugar fragment, 5'-CCU(2'AQ)AGCTAGG (1), is described. The anthraquinonylmethyl g...

A phosphorbisamidite approach to the synthesis of oligodeoxyribonucleotides and their analogues.

Nucleic Acids Symp. Ser. (21) , 31-2, (1989)

Utilities of deoxyribonucleoside 3'-O-phosphorbisdiethylamidites in the synthesis of oligodeoxyribonucleotides and their analogues are described.