(+)-Trans-limonene1,2-epoxide

Names

[ Name ]:
(+)-Trans-limonene1,2-epoxide

[Synonym ]:
(1S,2R,4R)-4-Isopropenyl-1-methyl-1-cyclohexene 1,2-epoxide
D-LIMONENE 1,2-EPOXIDE
(1S,2R,4R)-limonene 1,2-oxide
(1S,4R)-1,2-Epoxy-p-menth-8-ene
(1R,4S)-trans-limonene oxide
(4R)-limonene 1alpha,2alpha-epoxide
(+)-trans-Limonene oxide
(1S,2R,4R)-limonene-1,2-epoxide
(+)-trans-p-Mentha-1,8-diene 1,2-epoxide
(+)-trans-Limonene 1,2-epoxide
(1S,2R,4R)-trans-1,2-limonene epoxide
(1S,2R)-1,2-epoxy-p-menth-8-ene
(1R,3R,6S)-6-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptane
2a2g
trans-d-Limonene oxide
limonene oxide
LEO

Chemical & Physical Properties

[ Density]:
0.930 g/mL at 20ºC(lit.)

[ Molecular Formula ]:
C₁₀H₁₆O

[ Molecular Weight ]:
152.23300

[ Flash Point ]:
65ºC

[ Exact Mass ]:
152.12000

[ PSA ]:
12.53000

[ LogP ]:
2.52010

[ Index of Refraction ]:
n20/D 1.466

[ Storage condition ]:
2-8°C

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2932999099

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Catalytic mechanism of limonene epoxide hydrolase, a theoretical study.

J. Am. Chem. Soc. 127(41) , 14339-47, (2005)

The catalytic mechanism of limonene epoxide hydrolase (LEH) was investigated theoretically using the density functional theory method B3LYP. LEH is part of a novel limonene degradation pathway found i...

QM/MM study of the mechanism of enzymatic limonene 1,2-epoxide hydrolysis.

Biochim. Biophys. Acta 1824(2) , 263-8, (2012)

Limonene 1,2-epoxide hydrolase (LEH) is completely different from those of classic epoxide hydrolases (EHs) which catalyze the hydrolysis of epoxides to vicinal diols. A novel concerted general acid c...

Total synthesis of (+)-cymbodiacetal: a re-evaluation of the biomimetic route.

J. Org. Chem. 75(24) , 8465-70, (2010)

A total synthesis of (+)-cymbodiacetal (1) has been completed from (R)-(+)-limonene oxide using a hetero-Diels-Alder cycloaddition as a key step. The key Diels-Alder cycloaddition proceeds with endo-s...