2,2,2-Trichloroethoxysulfonamide
Names
[ CAS No. ]:
69226-51-3
[ Name ]:
2,2,2-Trichloroethoxysulfonamide
[Synonym ]:
sulfamate de trichloro-2,2,2 ethyle
CCl3CH2OSO2NH2
2,2,2-trichloroethoxysulfonyl amine
1,1,1-trichloroethylsulfamate ester
2,2,2-Trichloroethoxysulfonamide
Sulfamic acid,2,2,2-trichloroethyl ester
2,2,2,3',4'-PENTAFLUOROACETOPHENONE
Chemical & Physical Properties
[ Density]:
1.801g/cm3
[ Boiling Point ]:
288.7ºC at 760 mmHg
[ Melting Point ]:
56 °C
[ Molecular Formula ]:
C2H4Cl3NO3S
[ Molecular Weight ]:
228.48200
[ Flash Point ]:
128.4ºC
[ Exact Mass ]:
226.89800
[ PSA ]:
77.77000
[ LogP ]:
2.35780
[ Index of Refraction ]:
1.543
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- WO6200000
- CHEMICAL NAME :
- Sulfamic acid, 2,2,2-trichloroethyl ester
- CAS REGISTRY NUMBER :
- 69226-51-3
- LAST UPDATED :
- 199012
- DATA ITEMS CITED :
- 1
- MOLECULAR FORMULA :
- C2-H4-Cl3-N-O3-S
- MOLECULAR WEIGHT :
- 228.48
- WISWESSER LINE NOTATION :
- ZSWO1XGGG
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- MECHAN Medicinal Chemistry, A Series of Reviews. (New York, NY) V.1-6, 1951-63. Discontinued. Volume(issue)/page/year: 6,223,1963
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ RIDADR ]:
NONH for all modes of transport
[ RTECS ]:
WO6200000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
J. Am. Chem. Soc. 129 , 562, (2007)
Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstit...