4-Bromo-3-methylaniline

Names

[ Name ]:
4-Bromo-3-methylaniline

[Synonym ]:
4-bromo-3-methylbenzenamine
EINECS 230-056-3
Benzenamine, 4-bromo-3-methyl-
Benzenamine,4-bromo-3-methyl
4-Bromo-m-toluidine
2-bromo-5-aminotoluene
5-Amino-2-bromotoluene
4-Bromo-3-methylaniline
MFCD00007828
4-bromo-3-methyl-aniline
amino-5-bromo-2-toluene
3-Methyl-4-bromoaniline

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
240.0±0.0 °C at 760 mmHg

[ Melting Point ]:
80-82 °C(lit.)

[ Molecular Formula ]:
C₇H₈BrN

[ Molecular Weight ]:
186.049

[ Flash Point ]:
101.2±21.8 °C

[ Exact Mass ]:
184.984009

[ PSA ]:
26.02000

[ LogP ]:
2.51

[ Vapour Pressure ]:
0.0±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.609

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R33;R36/37/38

[ Safety Phrases ]:
S26-S37/39-S24/25

[ RIDADR ]:
UN2811

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2921430090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2921430090

[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Multikilogram-scale synthesis of a biphenyl carboxylic acid derivative using a Pd/C-mediated suzuki coupling approach.

Org. Process Res. Dev. 3(4) , 248-252, (1999)