Trimethyl orthobenzoate
Names
[ CAS No. ]:
707-07-3
[ Name ]:
Trimethyl orthobenzoate
[Synonym ]:
EINECS 211-897-5
(Trimethoxymethyl)benzene
trimethoxymethylbenzene
MFCD00008474
Benzene, (trimethoxymethyl)-
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
223.9±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C10H14O3
[ Molecular Weight ]:
182.216
[ Flash Point ]:
82.2±0.0 °C
[ Exact Mass ]:
182.094299
[ PSA ]:
27.69000
[ LogP ]:
3.70
[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.481
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36/37/39-S37/39
[ WGK Germany ]:
3
[ HS Code ]:
2909309090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2909309090
[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Inorg. Chem. 40(8) , 1865-70, (2001)
Reaction of P-dimethylaminophosphonic acid bis(1-methylhydrazide) (6) with trimethyl orthobenzoate gave 1,2,5,6-tetrahydro-1,5-dimethyl-6-(N,N-dimethylamino)-6-phenyl-1,2,4,5,6-tetrazaphosphorine-6-ox...
Reactions between pyrrole and orthoesters: preparation of tri-(pyrrol-2-yl) alkanes. Reese CB and Yan H.Tetrahedron Lett. 43(32) , 5545-47, (2001)
Incidence and avoidance of stereospecific 1, 2-ethylthio group migration during the synthesis of ethyl 1-thio-a-l-rhamnopyranoside 2, 3-orthoester. Auzanneau F-I and Bundle DR.
Carbohydr. Res. 212 , 13-24, (1991)