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2-(Difluoromethoxy)benzaldehyde

Names

[ CAS No. ]:
71653-64-0

[ Name ]:
2-(Difluoromethoxy)benzaldehyde

[Synonym ]:
Benzaldehyde, 2-(difluoromethoxy)-
MFCD00042251
2-(Difluoromethoxy)benzaldehyde
α,α-Difluoro-o-anisaldehyde
VHR BOYFF

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
226.6±30.0 °C at 760 mmHg

[ Molecular Formula ]:
C8H6F2O2

[ Molecular Weight ]:
172.129

[ Flash Point ]:
88.4±19.4 °C

[ Exact Mass ]:
172.033585

[ PSA ]:
26.30000

[ LogP ]:
1.89

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.498

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2913000090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2913000090

[ Summary ]:
HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%

Articles

Effect of acyl chain length and branching on the enantioselectivity of Candida rugosa lipase in the kinetic resolution of 4-(2-difluoromethoxyphenyl)-substituted 1,4-dihydropyridine 3,5-diesters.

J. Org. Chem. 67(2) , 401-10, (2002)

Since 2,6-dimethyl-4-aryl-1,4-dihydropyridine 3,5-diesters themselves are not hydrolyzed by commercially available hydrolases, derivatives with spacers containing a hydrolyzable group were prepared. S...

Synthesis of 3-alkoxycarbonyl-6-alkylsulfanyl-4-[2-(difluoromethoxy) phenyl]-1, 4-dihydropyridines and related derivatives as analogs of cognition enhancer cerebrocrast. Krauze A, et al.

Chem. Heterocycl. Comp. 49(4) , 566-73, (2013)

Synthesis and enantioselective lipase-catalyzed kinetic resolution of methyl 6-(methoxycarbonyl-methyl) sulfanyl-1, 4-dihydropyridine-3-carboxylates. Andzans Z, et al.

Chem. Heterocycl. Comp. 49(13) , 421-27, (2013)


More Articles


Related Compounds