Methyl bromopyruvate
Names
[ CAS No. ]:
7425-63-0
[ Name ]:
Methyl bromopyruvate
[Synonym ]:
Methyl 3-bromo-2-oxopropanoate
Propanoic acid, 3-bromo-2-oxo-, methyl ester
MFCD01862963
Methyl bromopyruvate
Chemical & Physical Properties
[ Density]:
1.7±0.1 g/cm3
[ Boiling Point ]:
186.8±23.0 °C at 760 mmHg
[ Molecular Formula ]:
C4H5BrO3
[ Molecular Weight ]:
180.985
[ Flash Point ]:
66.8±22.6 °C
[ Exact Mass ]:
179.942200
[ PSA ]:
43.37000
[ LogP ]:
0.21
[ Vapour Pressure ]:
0.7±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.468
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
UN 3334
[ WGK Germany ]:
3
[ HS Code ]:
2918300090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2918300090
[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%
Articles
Invest. Ophthalmol. Vis. Sci. 48(10) , 4688-93, (2007)
Inhibition of carbonic anhydrase in the eye is an important treatment modality for reducing the intraocular pressure in glaucoma. However, evidence suggests that carbonic anhydrase inhibition also exe...
Protecting-group-free total synthesis of (+/-)-subincanadine F.J. Org. Chem. 74(19) , 7533-5, (2009)
With chemoselective Dieckmann condensation as the key step, the protective-group-free total synthesis of (+/-)-subincanadine F was accomplished in 7 steps from the commercially available tryptamine in...
Further degradation products of cephalosporin C. Isolation and synthesis of 2-(4-amino-4-carboxybutyl)thiazole-4-carboxylic acid.Biochem. J. 75(2) , 216, (1960)