2-Methoxycyclohexanone

Names

[ Name ]:
2-Methoxycyclohexanone

[Synonym ]:
1,4-Dihydro-2-methoxybenzoesaeure
rac-2-methoxycyclohexanone
2,5-Cyclohexadiene-1-carboxylic acid,2-methoxy
2-methoxy-cyclohexanone
1-methoxycyclohexanone
EINECS 231-071-8
2-Methoxy-1.4-dihydrobenzoesaeure
2-Methoxy-cyclohexa-2,5-diencarbonsaeure
2-methoxy-cyclohexa-2,5-dienecarboxylic acid
(RS)-2-methoxycyclohexanone
MFCD00009610

Chemical & Physical Properties

[ Density]:
1.02 g/mL at 25 °C(lit.)

[ Boiling Point ]:
185 °C750 mm Hg(lit.)

[ Molecular Formula ]:
C₇H₁₂O₂

[ Molecular Weight ]:
128.16900

[ Flash Point ]:
157 °F

[ Exact Mass ]:
128.08400

[ PSA ]:
26.30000

[ LogP ]:
1.14450

[ Index of Refraction ]:
n20/D 1.455(lit.)

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Safety Information

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36/37/39

[ WGK Germany ]:
3

[ HS Code ]:
2914509090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2914509090

[ Summary ]:
HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Palladium(II)-catalyzed oxidation of aldehydes and ketones. 1. Carbonylation of ketones with carbon monoxide catalyzed by palladium(II) chloride in methanol.

J. Org. Chem. 66(1) , 180-5, (2001)

Unsubstituted or alkyl-substituted cyclic ketones react with PdCl2 in methanol under a CO atmosphere to give mainly acyclic diesters along with some acyclic chloro-substituted monoesters. The monosubs...

Infrared spectroscopy and theoretical calculations as tools for the conformational analysis of 2-methoxycyclohexanone.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 59(6) , 1177-82, (2003)

The conformational equilibrium of 2-methoxycyclohexanone has been analyzed through infrared spectroscopy and theoretical calculations. These calculations indicate that six conformations may be present...