2-Methyl-1-naphthol
Names
[ CAS No. ]:
7469-77-4
[ Name ]:
2-Methyl-1-naphthol
[Synonym ]:
2-Methyl-1-naphthol
EINECS 231-265-2
2-Methyl-1-naphthalenol
MFCD00003964
1-Naphthalenol, 2-methyl-
2-Methyl-α-naphthol
2-methylnaphthalen-1-ol
Chemical & Physical Properties
[ Density]:
1.1±0.1 g/cm3
[ Boiling Point ]:
304.3±11.0 °C at 760 mmHg
[ Melting Point ]:
64-66ºC(lit.)
[ Molecular Formula ]:
C11H10O
[ Molecular Weight ]:
158.197
[ Flash Point ]:
147.1±11.1 °C
[ Exact Mass ]:
158.073166
[ PSA ]:
20.23000
[ LogP ]:
3.17
[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C
[ Index of Refraction ]:
1.656
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H315-H318-H335
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
37/38-41
[ Safety Phrases ]:
26-39
[ RIDADR ]:
NONH for all modes of transport
[ HS Code ]:
2907199090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2907199090
[ Summary ]:
2907199090 other monophenols VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Dalton Trans. 41(32) , 9633-8, (2012)
Well hexagonally ordered NbSBA-15 catalysts synthesized by an efficient hydrothermal method were used, for the first time, for the selective synthesis of vitamin K(3) by liquid-phase oxidation of 2-me...
Mechanistic insights into oxidation of 2-methyl-1-naphthol with dioxygen: autoxidation or a spin-forbidden reaction?J. Phys. Chem. B 115(42) , 11971-83, (2011)
Oxidation of 2-methyl-1-naphthol (MNL) with molecular oxygen proceeds efficiently under mild reaction conditions (3 atm O(2), 60-80 °C) in the absence of any catalyst or sensitizer and produces 2-meth...
EPR study on the mechanism of H2O2-based oxidation of alkylphenols over titanium single-site catalysts. Zalomaeva OV, et al.J. Mol. Catal. A: Chem. 277(1) , 185-192, (2007)