(6-Butyl-5-decen-5-yl)-λ2-stannane
Names
[ CAS No. ]:
7486-35-3
[ Name ]:
(6-Butyl-5-decen-5-yl)-λ2-stannane
[Synonym ]:
Stannane, (1,2-dibutyl-1-hexen-1-yl)-
tributyl(ethenyl)stannane
(6-Butyl-5-decen-5-yl)-λ-stannane
EINECS 231-291-4
MFCD00009421
Chemical & Physical Properties
[ Density]:
1.085 g/mL at 25 °C(lit.)
[ Boiling Point ]:
104-106 °C3.5 mm Hg(lit.)
[ Melting Point ]:
<0ºC
[ Molecular Formula ]:
C14H30Sn
[ Molecular Weight ]:
315.082
[ Flash Point ]:
>230 °F
[ Exact Mass ]:
316.121307
[ LogP ]:
5.56070
[ Index of Refraction ]:
n20/D 1.478(lit.)
[ Storage condition ]:
Refrigerator
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS06, GHS08, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H226-H301-H312-H315-H319-H372-H410
[ Precautionary Statements ]:
Missing Phrase - N15.00950417-P210-P260-P280-P305 + P351 + P338-P370 + P378
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
T:Toxic;N:Dangerousfortheenvironment;
[ Risk Phrases ]:
R21;R25;R36/38;R48/23/25;R50/53
[ Safety Phrases ]:
S35-S36/37/39-S45-S60-S61
[ RIDADR ]:
UN 2788 6.1/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1
[ HS Code ]:
2931900090
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
J. Am. Chem. Soc. 125 , 3718, (2003)
This communication describes a significant expansion in the scope of Stille reactions of Csp3-X electrophiles, specifically, that Pd/P(t-Bu)2Me catalyzes the room-temperature cross-coupling of a varie...
Palladium-catalyzed homogeneous coupling reactions of steroids with organostannanes.Steroids 60(12) , 812-6, (1995)
Direct and carbonylative coupling reactions of various steroid derivatives possessing iodo- and bromo-alkenyl moiety (17-iodo-androst-16-ene, 1, 17-bromoandrost-2,16-diene, 2, 17-iodo-4-aza-4-methylan...
Palladium-catalyzed ring expansion reaction of (Z)-1-(1,3-butadienyl)cyclobutanols with aryl iodides. stereospecific synthesis of (Z)-2-(3-aryl-1-propenyl)cyclopentanones.Org. Lett. 6 , 1979-1982, (2004)
[reaction: see text] A novel type of cascade ring expansion process has been developed by the palladium-catalyzed reaction of (Z)-1-(1,3-butadienyl)cyclobutanols with aryl iodides. The reaction procee...