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Diiodomethane

Names

[ CAS No. ]:
75-11-6

[ Name ]:
Diiodomethane

[Synonym ]:
Diiodmethane
di-iodomethane
methylene diiodide
methane, di-iodo-
CH2I2
Methane, diiodo-
Diodomethane
Mi-gee brand
Methylenjodid
Mi-gee
Diiodmethan
Diiodomethane
METHYLENE IODIDE
diiodo-methan
EINECS 200-841-5
MFCD00001079
Dijodmethan

Chemical & Physical Properties

[ Density]:
3.2±0.1 g/cm3

[ Boiling Point ]:
182.0±0.0 °C at 760 mmHg

[ Melting Point ]:
6 °C

[ Molecular Formula ]:
CH2I2

[ Molecular Weight ]:
267.836

[ Flash Point ]:
76.6±13.9 °C

[ Exact Mass ]:
267.824585

[ LogP ]:
2.30

[ Vapour density ]:
9.25 (vs air)

[ Vapour Pressure ]:
1.1±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.719

[ Stability ]:
Stable. Incompatible with strong oxidizing agents, strong bases. Reacts violently with alkali metal salts. May discolour on exposure to light.

[ Water Solubility ]:
14 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
PA8575000
CHEMICAL NAME :
Methane, diiodo-
CAS REGISTRY NUMBER :
75-11-6
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C-H2-I2
MOLECULAR WEIGHT :
267.83
WISWESSER LINE NOTATION :
I1I

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - child
DOSE/DURATION :
2778 uL/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
AEMED3 Annals of Emergency Medicine. (American College of Emergency Physicians, 1125 Executive Circle, Irving, TX 75038) Volume(issue)/page/year: 19,1171,1990
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
403 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,756,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
467 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,756,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
830 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 4,354,1962 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1158 No. of Facilities: 31 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 311 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1158 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 42 (estimated)

Safety Information

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
2810

[ WGK Germany ]:
3

[ RTECS ]:
PA8575000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
29033080

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 29033080


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