Lithium hydride
Names
[ CAS No. ]:
7580-67-8
[ Name ]:
Lithium hydride
[Synonym ]:
EINECS 231-484-3
MFCD00011074
LiH
hydride lithium
Lithium hydride
Chemical & Physical Properties
[ Density]:
0.82
[ Boiling Point ]:
850(分解)
[ Melting Point ]:
680ºC
[ Molecular Formula ]:
LiH
[ Molecular Weight ]:
7.949
[ Exact Mass ]:
8.023829
[ Water Solubility ]:
reacts
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- OJ6300000
- CHEMICAL NAME :
- Lithium hydride
- CAS REGISTRY NUMBER :
- 7580-67-8
- LAST UPDATED :
- 199806
- DATA ITEMS CITED :
- 27
- MOLECULAR FORMULA :
- H-Li
- MOLECULAR WEIGHT :
- 7.95
- WISWESSER LINE NOTATION :
- LI H
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 10 mg/m3/4H
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - cough
- REFERENCE :
- AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 14,468,1956 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 5 mg/m3/4H/1W-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Skin and Appendages - dermatitis, other (after systemic exposure)
- REFERENCE :
- AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 14,468,1956
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 5 mg/m3/4H/1W-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Skin and Appendages - dermatitis, other (after systemic exposure)
- REFERENCE :
- AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 14,468,1956
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 5 mg/m3/4H/1W-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - effect, not otherwise specified Skin and Appendages - dermatitis, other (after systemic exposure)
- REFERENCE :
- AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 14,468,1956
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 5 mg/m3/4H-I
- REFERENCE :
- AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 14,468,1956 *** REVIEWS *** ACGIH TLV-TWA 0.025 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.025 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,147,1971 OSHA PEL (Gen Indu):8H TWA 0.025 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.025 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.025 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.025 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.025 mg/m3 JAN 1993 OEL-BELGIUM:TWA 0.025 mg/m3 JAN 1993 OEL-DENMARK:TWA 0.025 mg/m3 JAN 1993 OEL-FINLAND:TWA 0.025 mg/m3;STEL 0.075 mg/m3 JAN 1993 OEL-FRANCE:TWA 0.025 mg/m3 JAN 1993 OEL-GERMANY:TWA 0.025 mg/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.025 mg/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.025 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.025 mg/m3 JAN 1993 OEL-TURKEY:TWA 0.025 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.025 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO LITHIUM HYDRIDE-air:10H TWA 0.025 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 43115 No. of Facilities: 11 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 11 (estimated)
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H260-H301-H314
[ Supplemental HS ]:
Reacts violently with water.
[ Precautionary Statements ]:
P223-P231 + P232-P280-P301 + P310-P370 + P378-P422
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ Hazard Codes ]:
C:Corrosive
[ Risk Phrases ]:
R14/15;R25;R34
[ Safety Phrases ]:
S25-S36/37/39-S45-S7/8
[ RIDADR ]:
UN 1414/2805
[ WGK Germany ]:
2
[ RTECS ]:
OJ6300000
[ Packaging Group ]:
I
[ Hazard Class ]:
4.3
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
J. Sci. Ind. Res. 65(10) , 808, (2006)
Drug-induced liver injury (DILI) is a significant concern in drug development due to the poor concordance between preclinical and clinical findings of liver toxicity. We hypothesized that the DILI typ...
Nanoarchitecture of Protective Coatings for Air Sensitive Metal Hydrides Dobbins T, et. al.Material Matters 2(2) , 19, (2007)
Spectroscopy and structure of the lithium hydride diatomic molecules and ions. Stwalley WC and Zemke WT
J. Phys. Chem. 22(1) , 87-112, (1993)