Chlorotriphenylsilane

Names

[ CAS No. ]:
76-86-8

[ Name ]:
Chlorotriphenylsilane

[Synonym ]:
Benzene, 1,1',1''-(chlorosilylidyne)tris-
Triphenylsilyl chloride
Chloro(triphenyl)silane
Chlorotriphenylsilane
triphenylsilylchloride
Triphenylchlorosilane
EINECS 200-989-0
MFCD00000496

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
374.8±15.0 °C at 760 mmHg

[ Melting Point ]:
91-94 °C(lit.)

[ Molecular Formula ]:
C₁₈H₁₅ClSi

[ Molecular Weight ]:
294.850

[ Flash Point ]:
164.5±10.3 °C

[ Exact Mass ]:
294.063141

[ LogP ]:
7.43

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.614

[ Water Solubility ]:
acetone: 0.1 g/mL, clear

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: VV2720000

CHEMICAL NAME :: Silane, chlorotriphenyl-

CAS REGISTRY NUMBER :: 76-86-8

BEILSTEIN REFERENCE NO. :: 1820487

LAST UPDATED :: 199709

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C18-H15-Cl-Si

MOLECULAR WEIGHT :: 294.87

WISWESSER LINE NOTATION :: G-SI-R&R&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 56 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04717 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4623 No. of Facilities: 4 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 280 (estimated) No. of Female Employees: 4 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S24/25

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
VV2720000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
29310095

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 29310095

Articles

[Preparation of phenyl treated packing materials for high-performance liquid chromatography: evaluation by retention behaviour of carbamazepine and diphenylhydantoin].

Yakugaku Zasshi 112(6) , 409-13, (1992)

The retention behavior and selectivity of 30 kinds of phenyl-modified porous glasses and silicas, prepared from solutions of phenyldimethylchlorosilane, diphenylmethylchlorosilane or triphenylchlorosi...