trifluoromethanesulfonimide
Names
[ CAS No. ]:
82113-65-3
[ Name ]:
trifluoromethanesulfonimide
[Synonym ]:
1,1,1-trifluoro-N-(trifluoromethylsulfonyl)methanesulfonamide
MFCD00214154
Bis(trifluoromethane)sulfonimide
N,N-Bis(trifluoromethanesulfonyl)imide
Chemical & Physical Properties
[ Density]:
1.936 g/cm3
[ Boiling Point ]:
90-91 °C(lit.)
[ Melting Point ]:
52-56 °C
[ Molecular Formula ]:
C2HF6NO4S2
[ Molecular Weight ]:
281.15400
[ Flash Point ]:
69ºC
[ Exact Mass ]:
280.92500
[ PSA ]:
97.07000
[ LogP ]:
2.82770
[ Index of Refraction ]:
1.523
[ Storage condition ]:
2-8°C
[ Stability ]:
Stable. Incompatible with strong oxidizing agents. Reacts violently with water.
MSDS
Safety Information
[ Symbol ]:
GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314
[ Supplemental HS ]:
Reacts violently with water.
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ Hazard Codes ]:
C
[ Risk Phrases ]:
R34;R40
[ Safety Phrases ]:
S26-S36/37/39-S45
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Hazard Class ]:
8.0
[ HS Code ]:
2935009090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2935009090
[ Summary ]:
2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%
Articles
J. Organomet. Chem. 646(1) , 171-8, (2002)
Comparative Electrochemical Study of New Poly(oxyethylene)-Li Salt Complexes. Benrabah D, et al.
J. Chem. Soc., Faraday 89 , 355-359, (1993)
Synthesis of trehalose mimics by bismuth (III) triflate or bis (trifluoromethane) sulfonimide-catalyzed 1-C-methyl-D-hexopyranosylation. Yamanoi T, et al.
Tetrahedron Asymmetry 17(20) , 2914-2918, (2006)