(3-Bromophenyl)boronic acid
Names
[ CAS No. ]:
89598-96-9
[ Name ]:
(3-Bromophenyl)boronic acid
[Synonym ]:
(3-Bromophenyl)boronic acid
Boronic acid, B-(3-bromophenyl)-
MFCD00239386
Biological Activity
[Description]:
[Related Catalog]:
Chemical & Physical Properties
[ Density]:
1.7±0.1 g/cm3
[ Boiling Point ]:
330.5±44.0 °C at 760 mmHg
[ Melting Point ]:
164-168 °C(lit.)
[ Molecular Formula ]:
C6H6BBrO2
[ Molecular Weight ]:
200.83
[ Flash Point ]:
153.7±28.4 °C
[ Exact Mass ]:
199.964417
[ PSA ]:
40.46000
[ LogP ]:
2.36
[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C
[ Index of Refraction ]:
1.598
[ Storage condition ]:
0-6°C
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S37/39-S26
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2931900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Org. Lett. 6 , 2205-2207, (2004)
[reaction: see text] A mixture of nitrate salt and chlorotrimethylsilane is found to be an efficient regioselective nitrating agent for the ipso-nitration of arylboronic acids to produce the correspon...