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Benzoic anhydride

Names

[ CAS No. ]:
93-97-0

[ Name ]:
Benzoic anhydride

[Synonym ]:
Benzoic acid anhydride
Benzoyl benzoate
MFCD00003073
benzoyl anhydride
EINECS 202-291-1
Benzoic anhydride

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
360.0±11.0 °C at 760 mmHg

[ Melting Point ]:
38-42 °C(lit.)

[ Molecular Formula ]:
C14H10O3

[ Molecular Weight ]:
226.227

[ Flash Point ]:
168.4±16.5 °C

[ Exact Mass ]:
226.062988

[ PSA ]:
43.37000

[ LogP ]:
3.02

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.590

[ Storage condition ]:
Store at RT.

[ Water Solubility ]:
0.01 g/L

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H315-H318-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S39-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
5.1

[ HS Code ]:
4002191900

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 4002191900

Articles

Regioselective benzoylation of glycopyranosides by benzoic anhydride in the presence of Cu(CF3COO)2.

Carbohydr. Res. 359 , 111-9, (2012)

Benzoylation of methyl and benzyl glycopyranosides by benzoic anhydride in acetonitrile in the presence of copper(II) trifluoroacetate as a promoter has given monobenzoates with a good yield and high ...

Introduction of a benzoyl group onto 6-chloropurine riboside in aqueous solution and its application to the synthesis of nucleoside derivatives.

Nucleic Acids Symp. Ser. 44 , 103-104, (2000)

A benzoyl group was introduced onto the 3'-hydroxyl group of 6-chloropurine riboside by treatment with benzoic anhydride in the presence of a base in aqueous solution. The product (3b) was converted t...

Derivatization for LC-electrospray ionization-MS: a tool for improving reversed-phase separation and ESI responses of bases, ribosides, and intact nucleotides.

Anal. Chem. 76(10) , 2869-77, (2004)

We have developed a method for analyzing polar compounds by reversed-phase LC-ESI-MS following esterification of the analytes' free hydroxyl groups with propionyl or benzoyl acid anhydride. The method...


More Articles


Related Compounds