Benzoic anhydride
Names
[ CAS No. ]:
93-97-0
[ Name ]:
Benzoic anhydride
[Synonym ]:
Benzoic acid anhydride
Benzoyl benzoate
MFCD00003073
benzoyl anhydride
EINECS 202-291-1
Benzoic anhydride
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
360.0±11.0 °C at 760 mmHg
[ Melting Point ]:
38-42 °C(lit.)
[ Molecular Formula ]:
C14H10O3
[ Molecular Weight ]:
226.227
[ Flash Point ]:
168.4±16.5 °C
[ Exact Mass ]:
226.062988
[ PSA ]:
43.37000
[ LogP ]:
3.02
[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C
[ Index of Refraction ]:
1.590
[ Storage condition ]:
Store at RT.
[ Water Solubility ]:
0.01 g/L
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H315-H318-H335
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S39-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ Packaging Group ]:
I; II; III
[ Hazard Class ]:
5.1
[ HS Code ]:
4002191900
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 4002191900
Articles
Carbohydr. Res. 359 , 111-9, (2012)
Benzoylation of methyl and benzyl glycopyranosides by benzoic anhydride in acetonitrile in the presence of copper(II) trifluoroacetate as a promoter has given monobenzoates with a good yield and high ...
Introduction of a benzoyl group onto 6-chloropurine riboside in aqueous solution and its application to the synthesis of nucleoside derivatives.Nucleic Acids Symp. Ser. 44 , 103-104, (2000)
A benzoyl group was introduced onto the 3'-hydroxyl group of 6-chloropurine riboside by treatment with benzoic anhydride in the presence of a base in aqueous solution. The product (3b) was converted t...
Derivatization for LC-electrospray ionization-MS: a tool for improving reversed-phase separation and ESI responses of bases, ribosides, and intact nucleotides.Anal. Chem. 76(10) , 2869-77, (2004)
We have developed a method for analyzing polar compounds by reversed-phase LC-ESI-MS following esterification of the analytes' free hydroxyl groups with propionyl or benzoyl acid anhydride. The method...