2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE
Names
[ CAS No. ]:
95452-06-5
[ Name ]:
2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE
[Synonym ]:
2-TBS-1,3-dithiane
TBS-1,3-dithiane
2-(tert-butyldimethylsilyl)-1,3-dithiane
1-tert-butyldimethylsilyl(1,3)dithiane
2-TBS-1,3-dithinane
MFCD02093667
tert-butyl(1,3-dithian-2-yl)dimethylsilane
t-Butyl[1,3]dithian-2-yldimethylsilane
Chemical & Physical Properties
[ Density]:
1.01 g/mL at 25ºC(lit.)
[ Boiling Point ]:
124ºC5 mm Hg(lit.)
[ Molecular Formula ]:
C10H22S2Si
[ Molecular Weight ]:
234.49700
[ Flash Point ]:
221 °F
[ Exact Mass ]:
234.09300
[ PSA ]:
50.60000
[ LogP ]:
4.65020
[ Index of Refraction ]:
n20/D 1.531(lit.)
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2934999090
Customs
[ HS Code ]: 2934999090
[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
Org. Lett. 1(12) , 2001-4, (1999)
[formula: see text] An efficient synthesis of trisacetonide (+)-11, the Schreiber C(16-28) subtarget for mycoticins A and B, is described. The key synthetic transformation entails a one-flask, five-co...
A general, convergent strategy for the construction of indolizidine alkaloids: total syntheses of (-)-indolizidine 223AB and alkaloid (-)-205B.J. Org. Chem. 71 , 2547, (2006)
N-Toluenesulfonyl aziridines comprise effective second electrophiles in the solvent controlled three-component linchpin union of silyl dithianes for the stereocontrolled convergent elaboration of prot...
Total synthesis of the neotropical poison-frog alkaloid (-)-205B.Org. Lett. 7 , 3247, (2005)
[reaction: see text]. A stereocontrolled total synthesis of the neotropical poison-frog alkaloid (-)-205B (1) has been achieved, employing a dithiane three-component linchpin coupling, a one-pot seque...