(2,6-Bis((di(piperidin-1-yl)phosphino)amino)phenyl)palladium(II) chloride

Names

[ CAS No. ]:
955035-37-7

[ Name ]:
(2,6-Bis((di(piperidin-1-yl)phosphino)amino)phenyl)palladium(II) chloride

[Synonym ]:
1-N,3-N-bis[di(piperidin-1-yl)phosphanyl]benzene-2-ide-1,3-diamine,chloropalladium(1+)

Chemical & Physical Properties

[ Molecular Formula ]:
C₂₆H₄₅ClN₆P₂Pd

[ Molecular Weight ]:
645.49600

[ Exact Mass ]:
644.19000

[ PSA ]:
64.20000

[ LogP ]:
3.60960

MSDS

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Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

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Articles

Comparative Study of the Frech Catalyst with Two Conventional Catalysts in the Heck Synthesis of 2,4-Diaminopyrimidine-based Antibiotics.

Org. Prep. Proced. Int. 45(1) , 66-71, (2013)

Short, facile, and high-yielding synthesis of extremely efficient pincer-type suzuki catalysts bearing aminophosphine substituents.

Angew. Chem. Int. Ed. Engl. 46 , 6514-6517, (2007)

Rationally designed pincer-type heck catalysts bearing aminophosphine substituents: Pd IV intermediates and palladium nanoparticles.

Chemistry 14 , 7969-7977, (2008)

The aminophosphine-based pincer complexes [C6H3-2,6-(XP(piperidinyl)2)2Pd(Cl)] (X=NH 1; X=O 2) are readily prepared from cheap starting materials by sequential addition of 1,1',1''-phosphinetriyltripi...