2,4-Dinitrodiphenylamine
Names
[ CAS No. ]:
961-68-2
[ Name ]:
2,4-Dinitrodiphenylamine
[Synonym ]:
2,4-DINITRO-N-PHENYLBENZENAMINE
2,4-Dinitro-N-phenylaniline
2,4-Dinitrodiphenylamine
Benzenamine, 2,4-dinitro-N-phenyl-
N1-phenyl-2,4-dinitroaniline
MFCD00007223
EINECS 213-508-4
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
413.8±35.0 °C at 760 mmHg
[ Melting Point ]:
159-161 °C(lit.)
[ Molecular Formula ]:
C12H9N3O4
[ Molecular Weight ]:
259.218
[ Flash Point ]:
204.1±25.9 °C
[ Exact Mass ]:
259.059296
[ PSA ]:
103.67000
[ LogP ]:
4.11
[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C
[ Index of Refraction ]:
1.693
[ Stability ]:
Stable. Incompatible with strong bases, strong acids, strong oxidizing agents.
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- JJ8825000
- CHEMICAL NAME :
- Diphenylamine, 2,4-dinitro-
- CAS REGISTRY NUMBER :
- 961-68-2
- BEILSTEIN REFERENCE NO. :
- 1996954
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C12-H9-N3-O4
- MOLECULAR WEIGHT :
- 259.24
- WISWESSER LINE NOTATION :
- WNR CNW DMR
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 180 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#06394
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ RTECS ]:
JJ8825000
[ HS Code ]:
2921440000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2921440000
[ Summary ]:
2921440000. diphenylamine and its derivatives; salts thereof. VAT:17.0%. Tax rebate rate:17.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
Analyst 139(23) , 6232-41, (2014)
A method based on scanning laser ablation and inductively coupled plasma-mass spectrometry (SLA-ICPMS) and Raman micro-spectroscopy for the detection and identification of compounds consistent with gu...
Reduction of Nitrated Diphenylamine Derivatives under Anaerobic Conditions.Appl. Environ. Microbiol. 61(9) , 3282-7, (1995)
2-Nitrodiphenylamine, 4-nitrodiphenylamine, and 2,4-dinitrodiphenylamine were anaerobically metabolized in sediment-water batch enrichments inoculated with mud from the German North Sea coast. The fir...
A simple and efficient anionic chromogenic chemosensor based on 2,4-dinitrodiphenylamine in dimethyl sulfoxide and in dimethyl sulfoxide-water mixtures.Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 75(2) , 799-806, (2010)
Solutions of 2,4-dinitrodiphenylamine (1) in dimethylsulfoxide (DMSO) are colorless but upon deprotonation they become red. Addition of various anionic species (HSO(4)(-), H(2)PO(4)(-), NO(3)(-), CN(-...