Isobutyric acid anhydride
Names
[ CAS No. ]:
97-72-3
[ Name ]:
Isobutyric acid anhydride
[Synonym ]:
1Y1&VOVY1&1
Isobutyric acid anhydride
MFCD00008913
2-Methylpropanoic anhydride
2-methylpropanoyl 2-methylpropanoate
Propanoic acid, 2-methyl-, anhydride
EINECS 202-603-6
Isobutyric anhydride
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
183.6±8.0 °C at 760 mmHg
[ Melting Point ]:
-53 °C
[ Molecular Formula ]:
C8H14O3
[ Molecular Weight ]:
158.195
[ Flash Point ]:
59.4±0.0 °C
[ Exact Mass ]:
158.094299
[ PSA ]:
43.37000
[ LogP ]:
1.27
[ Vapour density ]:
5.45 (vs air)
[ Vapour Pressure ]:
0.8±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.418
[ Water Solubility ]:
decomposes
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H301 + H311-H314
[ Precautionary Statements ]:
P280-P301 + P310-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C:Corrosive;
[ Risk Phrases ]:
R21/22;R34
[ Safety Phrases ]:
S26-S36/37/39-S45
[ RIDADR ]:
2922
[ WGK Germany ]:
3
[ RTECS ]:
NQ5550000
[ Packaging Group ]:
II
[ Hazard Class ]:
8
[ HS Code ]:
2915900090
Synthetic Route
Customs
[ HS Code ]: 2915900090
[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%
Articles
J. Am. Chem. Soc. 129(42) , 12890-5, (2007)
An organocatalytic method for the chemo- and regioselective acylation of monosaccharides has been developed. Treatment of octyl beta-D-glucopyranoside with isobutyric anhydride in the presence of 10 m...
Theoretical prediction of selectivity in kinetic resolution of secondary alcohols catalyzed by chiral DMAP derivatives.J. Am. Chem. Soc. 134(22) , 9390-9, (2012)
The mechanism of esterification of the secondary alcohol 1-(1-naphthyl)ethanol 9 by isobutyric anhydride catalyzed by 4-pyrrolidinopyridine (PPY, 11) and a series of single enantiomer atropisomeric 4-...
Three-Component Supramolecular System with Multistimuli-Responsive Properties in Water.Chem. Asian J. 10 , 1690-7, (2015)
Hyperbranched polyethylenimine terminated with isobutyramide groups (HPEI-IBAm), 4-(phenylazo)benzoic acid (PABA), and α-cyclodextrin (α-CD) were assembled together at pH≈7 to form the three-component...