Di-1,3-cyclopentadien-1-ylruthenium
Names
[ CAS No. ]:
1287-13-4
[ Name ]:
Di-1,3-cyclopentadien-1-ylruthenium
[Synonym ]:
Bis(cyclopentadienyl)ruthenium
Di-1,3-cyclopentadien-1-ylruthenium
Ruthenium, di-1,3-cyclopentadien-1-yl-
Bis(cyclopentadienyl)ruthenium(II)
EINECS 215-065-2
Ruthenocene
MFCD00001442
Chemical & Physical Properties
[ Boiling Point ]:
41.5ºC at 760 mmHg
[ Melting Point ]:
199-201 °C(lit.)
[ Molecular Formula ]:
C10H10Ru
[ Molecular Weight ]:
231.256
[ Exact Mass ]:
231.982635
[ LogP ]:
2.04300
[ Vapour Pressure ]:
418mmHg at 25°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
Synthetic Route
Articles
J. Med. Chem. 48 , 2814-21, (2005)
A series of ruthenocene derivatives, 1-[4-(O(CH(2))(n)()N(CH(3))(2))phenyl]-1-(4-hydroxyphenyl)-2-ruthenocenylbut-1-ene, with n = 2-5, based on the structure of the breast cancer drug tamoxifen has be...
Group 8 metallocenes as bulky functional groups in glucopyranosides.Carbohydr. Res. 365 , 26-31, (2013)
The functionalization of methyl D-glucopyranosides at positions 4 and 6 with bulky moieties was carried out by using ferrocenyl and ruthenocenyl substituents. The synthesis succeeded by reaction of th...
Structural investigation of the interactions of biotinylruthenocene with avidin.Chem. Biol. Interact. 204(1) , 6-12, (2013)
The crystal structure of avidin, a protein from hen egg white, was determined in the form of a complex with biotinylruthenocene. This biotin-derived organometallic ligand is a potential anticancer age...