158923-07-0

158923-07-0 structure
158923-07-0 structure

Name cyclopentane,dicyclohexyl-[(1S)-1-(2-dicyclohexylphosphanylcyclopentyl)ethyl]phosphane,iron
Synonyms 1-{2-[P(cHex)2]-ferrocenyl}ethyl-P(cHex)2
1-[2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
(S)-1-[(RP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine
1-(Cy2P)-2-[1-(Cy2P)-ethyl]ferrocene
Josiphos SL-J003-2
CpFe[1-(Cy2P)-2-(CHMePCy2)C5H3]
(S)-(+)-1-[(R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL] ETHYLDICYCLOHEXYLPHOSPHINE
(S,S)-1-DICYCLOHEXYLPHOSPHINO-2-[1-(DICYCLOHEXYLPHOSPHINO)ETHYL]FERROCENE
Molecular Formula C36H56FeP2
Molecular Weight 606.62200
Exact Mass 606.32100
PSA 27.18000
LogP 11.13510

Section 1: Product Identification
Chemical Name:(S)-(+)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine, min. 97%
CAS Registry Number:158923-07-0
Formula:C36H56FeP2
EINECS Number:None
Chemical Family:organophosphine ligand
Synonym:[(R)-1-(S)-(+)-2(Dicyclohexylphosphanylethyl)dicyclohexyl phosphanylferrocene

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound158923-07-0100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and mucous membranes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, eyes
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards
Chronic Health Affects:
may be present.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Keep material in a tightly sealed container. Prolonged exposure to the air may result in degradation of the
Handling and Storage:
product. Handle in a hood with argon.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:orange powder
Molecular Weight:606.64
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:Insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:exposure to oxygen, contact with strong oxidizing agents
Incompatibility:Oxidizing agents and halogens
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides, and iron oxide.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A
Risk Phrases 36/37/38
Safety Phrases 26-36/37/39
WGK Germany 3