Name | Tetravinyl tin |
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Synonyms |
Stannane, tetraethenyl-
Stannane, tetravinyl- Tetravinylstannane MFCD00008608 tetrakis(ethenyl)stannane EINECS 214-193-6 TETRAVINYLTIN |
Density | 1.246 g/mL at 25 °C(lit.) |
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Boiling Point | 158.4±9.0 °C at 760 mmHg |
Molecular Formula | C8H12Sn |
Molecular Weight | 226.891 |
Flash Point | 40.6±0.0 °C |
Exact Mass | 227.996094 |
LogP | 5.88 |
Vapour Pressure | 3.4±0.3 mmHg at 25°C |
Index of Refraction | n20/D 1.501(lit.) |
Storage condition | Flammables area |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 10 23/24/25 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Flammable. Toxic by inhalation, in contact with skin and if swallowed.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. The toxicological properties of this material have not been fully investigated. Skin: May cause skin irritation. The toxicological properties of this material have not been fully investigated. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1112-56-7: United Kingdom, WEL - TWA: (listed as tin organic compounds): 0.1 mg/m3 TWA (except cyhexatin, as Sn) United Kingdom, WEL - STEL: (listed as tin organic compounds): 0. mg/m3 STEL (except cyhexatin, as Sn) United States OSHA: 0.1 mg/m3 TWA (as Sn) (listed under Tin orga compounds). Belgium - TWA: (listed as tin organic compounds): 0.1 mg/m3 VLE ( Sn) Belgium - STEL: (listed as tin organic compounds): 0.2 mg/m3 VLE Sn) France - VME: (listed as tin organic compounds): 0.1 mg/m3 VME (a Sn) France - VLE: (listed as tin organic compounds): 0.2 mg/m3 VLE (a Sn) Germany: (listed as tin organic compounds): 0.1 mg/m3 VME (as Sn) Germany: (listed as tin organic compounds): Skin absorber Malaysia: (listed as tin organic compounds): 0.1 mg/m3 TWA (as Sn Netherlands: (listed as tin organic compounds): 0.2 mg/m3 STEL (a Sn) Netherlands: (listed as tin organic compounds): 0.1 mg/m3 MAC (as Spain: (listed as tin organic compounds): 0.1 mg/m3 VLA-ED (as Sn Spain: (listed as tin organic compounds): 0.2 mg/m3 VLA-EC (as Sn Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: clear, colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 160 - 163 deg C Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 40 deg C ( 104.00 deg F) Explosion Limits, lower: N/A Explosion Limits, upper: N/A Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.2460g/cm3 Molecular Formula: Sn(CH=CH2)4 Molecular Weight: 226.88 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, ignition sources, excess heat. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1112-56-7 unlisted. LD50/LC50: Not available. Carcinogenicity: Tetravinyl Tin - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.* Hazard Class: 3 (6.1) UN Number: 1992 Packing Group: III IMO Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S. Hazard Class: 3.3 (6.1) UN Number: 1992 Packing Group: III RID/ADR Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S. Hazard Class: 3 (6.1) UN Number: 1992 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T Risk Phrases: R 10 Flammable. R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. Safety Phrases: S 9 Keep container in a well-ventilated place. S 16 Keep away from sources of ignition - No smoking. S 28A After contact with skin, wash immediately with plenty of water. S 33 Take precautionary measures against static discharges. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 1112-56-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 1112-56-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1112-56-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Symbol |
GHS02, GHS06 |
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Signal Word | Danger |
Hazard Statements | H226-H301-H311-H331 |
Precautionary Statements | P261-P280-P301 + P310-P311 |
Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
Hazard Codes | T: Toxic; |
Risk Phrases | R10;R23/24/25 |
Safety Phrases | S36/37/39-S45 |
RIDADR | UN 1993 3/PG 3 |
WGK Germany | 3 |
Packaging Group | II |
Hazard Class | 6.1(a) |
HS Code | 2931900090 |
~73% 1112-56-7 |
Literature: Sn: Org.Verb.1, 1.1.1.14.1, page 129 - 133 |
~83% 1112-56-7 |
Literature: US2873287 , ; C.A., , p. 13108 US2965661 , ; C.A., , p. 6377 GB829243 , ; C.A., , p. 21139 |
~% 1112-56-7 |
Literature: Journal of the American Chemical Society, , vol. 79, p. 2137 |
~% 1112-56-7 |
Literature: Journal of the American Chemical Society, , vol. 79, p. 515 |
~% 1112-56-7 |
Literature: Journal of Organometallic Chemistry, , vol. 694, # 15 p. 2368 - 2374 |
~% 1112-56-7 |
Literature: Journal of Organometallic Chemistry, , vol. 277, # 2 p. 235 - 244 |
~% 1112-56-7 |
Literature: Sn: Org.Verb.1, 1.1.1.5.4.5, page 106 - 108 |
~% 1112-56-7 |
Literature: Sn: Org.Verb.1, 1.1.1.16.1.4.5, page 159 - 161 |
~% 1112-56-7 |
Literature: Inorganica Chimica Acta, , vol. 150, p. 287 - 292 |
Precursor 9 | |
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DownStream 10 | |
HS Code | 2931900090 |
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Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |