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149022-15-1

149022-15-1 structure
149022-15-1 structure
  • Name: MBTH hydrochloride hydrate
  • Chemical Name: 3-Methyl-2-Benzothiazolinone Hydrazone Hydrochloride
  • CAS Number: 149022-15-1
  • Molecular Formula: C8H10ClN3S
  • Molecular Weight: 215.703
  • Create Date: 2018-11-23 11:53:13
  • Modify Date: 2024-01-06 10:26:28

Name 3-Methyl-2-Benzothiazolinone Hydrazone Hydrochloride
Synonyms MBTH hydrochloride
2-Benzothiazolinone, 3-methyl-, hydrazone, hydrochloride
2-Benzothiazolinone, 3-methyl-, hydrazone, monohydrochloride (8CI)
(3-methyl-1,3-benzothiazol-2-ylidene)hydrazine,hydrochloride
2(3H)-BENZOTHIAZOLONE, 3-METHYL-, HYDRAZONE, MONOHYDROCHLORIDE
MFCD00149370
(2Z)-2-Hydrazono-3-methyl-2,3-dihydro-1,3-benzothiazole hydrochloride (1:1)
2(3H)-Benzothiazolone, 3-methyl-, hydrazone, hydrochloride
3-METHYL-2-BENZOTHIAZOLINONE HYDRAZONE HYDROCHLORIDE
3-methylbenzothiazol-2(3H)-one hydrazone monohydrochloride
3-methylbenzothiazol-2(3H)-one hydrazone hydrochloride
EINECS 238-428-7
2(3H)-Benzothiazolone, 3-methyl-, hydrazone, (2Z)-, hydrochloride (1:1)
2-Benzothiazolinone, 3-methyl-, hydrazone, monohydrochloride
3-Methyl-2(3H)-benzothiazolone hydrazone hydrochloride
Boiling Point 342.9ºC at 760 mmHg
Melting Point 276-278ºC
Molecular Formula C8H10ClN3S
Molecular Weight 215.703
Flash Point 161.2ºC
Exact Mass 215.028397
PSA 71.55000
LogP 2.51650
Vapour Pressure 7.31E-05mmHg at 25°C
Storage condition 2~8°C

Section 1. Chemical Product and Company Identification
3- Methyl-2-Benzothiazolinone Hydrazone Catalog
XX605, M2140
Common Name/
Number(s).
Trade Name
HCl
CAS#4338-98-1
Manufacturer
RTECSNot available.
SPECTRUM CHEMICAL MFG. CORP.
TSCATSCA 8(b) inventory: 3-
Methyl-2-Benzothiazolinone
Hydrazone HCl
Commercial Name(s)Not available.
CI#Not available.
SynonymNot available.
IN CASE OF EMERGENCY
3- Methyl-2-Benzothiazolinone Hydrazone HCl
Chemical Name
Chemical FamilyNot available.CALL (310) 516-8000
C8-H9-N3-S.HCl
Chemical Formula
SPECTRUM CHEMICAL MFG. CORP.

Section 2.Composition and Information on Ingredients
Exposure Limits
TWA (mg/m3)STEL (mg/m3) CEIL (mg/m3)
NameCAS #% by Weight
1) {3-} Methyl-2-Benzothiazolinone Hydrazone HCl4338-98-1100
Toxicological Data3- Methyl-2-Benzothiazolinone Hydrazone HCl
on IngredientsLD50: Not available.
LC50: Not available.

Section 3. Hazards Identification
Potential Acute Health Effects Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation (lung irritant).
Potential Chronic HealthCARCINOGENIC EFFECTS: Not available.
EffectsMUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
The substance is toxic to mucous membranes, upper respiratory tract.
Repeated or prolonged exposure to the substance can produce target organs damage.
3- Methyl-2-Benzothiazolinone Hydrazone
HCl

Section 4. First Aid Measures
Eye ContactCheck for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.
Skin ContactAfter contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin
with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated
clothing before reusing.
Serious Skin ContactWash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
InhalationAllow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious InhalationNot available.
IngestionDo not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible
indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen
tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek immediate medical attention.
Serious IngestionNot available.

Section 5. Fire and Explosion Data
Flammability of the Product May be combustible at high temperature.
Auto-Ignition Temperature Not available.
Flash PointsNot available.
Flammable LimitsNot available.
Products of CombustionThese products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), sulfur oxides (SO2, SO3...).
Fire Hazards in Presence of Not available.
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
and InstructionsLARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks onNot available.
Fire Hazards
Special Remarks on Explosion Not available.
Hazards

Section 6. Accidental Release Measures
Small SpillUse appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large SpillUse a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system.
3- Methyl-2-Benzothiazolinone Hydrazone
HCl

Section 7. Handling and Storage
PrecautionsKeep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the
residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust.
Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If
ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes
Keep away from incompatibles such as oxidizing agents.
StorageKeep container dry. Keep in a cool place. Ground all equipment containing material. Carcinogenic, teratogenic or
mutagenic materials should be stored in a separate locked safety storage cabinet or room.

Section 8. Exposure Controls/Personal Protection
Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal ProtectionSplash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spillto avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure LimitsNot available.

Section 9. Physical and Chemical Properties
Physical state and appearance Solid. (Crystalline solid.)OdorNot available.
TasteNot available.
215.7 g/mole
Molecular Weight
ColorOff-white.
pH (1% soln/water)Not available.
Boiling PointNot available.
Melting PointNot available.
Not available.
Critical Temperature
Specific GravityNot available.
Vapor PressureNot applicable.
Vapor DensityNot available.
VolatilityNot available.
Odor ThresholdNot available.
Water/Oil Dist. Coeff.Not available.
Not available.
Ionicity (in Water)
Dispersion PropertiesNot available.
Not available.
Solubility
3- Methyl-2-Benzothiazolinone Hydrazone
HCl

Section 10. Stability and Reactivity Data
StabilityThe product is stable.
Instability TemperatureNot available.
Conditions of InstabilityNot available.
Incompatibility with variousReactive with oxidizing agents.
substances
CorrosivityNot available.
Special Remarks onNot available.
Reactivity
Not available.
Special Remarks on
Corrosivity
PolymerizationNo.

Section 11. Toxicological Information
Routes of EntryAbsorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to AnimalsLD50: Not available.
LC50: Not available.
Chronic Effects on Humans The substance is toxic to mucous membranes, upper respiratory tract.
Other Toxic Effects onHazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant).
Humans
Special Remarks onNot available.
Toxicity to Animals
Special Remarks onNot available.
Chronic Effects on Humans
Special Remarks on otherNot available.
Toxic Effects on Humans

Section 12. Ecological Information
EcotoxicityNot available.
BOD5 and CODNot available.
Products of BiodegradationPossibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the ProductsThe products of degradation are less toxic than the product itself.
of Biodegradation
Special Remarks on theNot available.
Products of Biodegradation
3- Methyl-2-Benzothiazolinone Hydrazone
HCl

Section 13. Disposal Considerations
Waste Disposal

Section 14. Transport Information
DOT ClassificationNot a DOT controlled material (United States).
Not applicable.
Identification
Special Provisions forNot applicable.
Transport
DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
Federal and StateTSCA 8(b) inventory: 3- Methyl-2-Benzothiazolinone Hydrazone HCl
Regulations
CaliforniaCalifornia prop. 65: This product contains the following ingredients for which the State of California has found
Proposition 65to cause cancer which would require a warning under the statute: No products were found.
Warnings
California prop. 65: This product contains the following ingredients for which the State of California has found
to cause birth defects which would require a warning under the statute: No products were found.
Other RegulationsNot available..
WHMIS (Canada) Not controlled under WHMIS (Canada).
Other Classifications
DSCL (EEC)R20/21/22- Harmful by inhalation, in
contact with skin and if swallowed.
R36/37/38- Irritating to eyes,
respiratory system and skin.
R40- Possible risks of irreversible
effects.
Health Hazard
HMIS (U.S.A.)2 National Fire Protection
1 Flammability
1 Association (U.S.A.)
Fire Hazard
2 0 Reactivity
Health
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
3- Methyl-2-Benzothiazolinone Hydrazone
HCl
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment
Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes T:Toxic;
Risk Phrases R25;R36
Safety Phrases S26-S36-S45
RIDADR UN 2811
WGK Germany 3.0
Packaging Group III
Hazard Class 6.1
HS Code 2934200090
HS Code 2934200090
Summary 2934200090. other compounds containing in the structure a benzothiazole ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%