91159-11-4

91159-11-4 structure
91159-11-4 structure
  • Name: 1,3-bis(di-i-propylphosphino)propane
  • Chemical Name: 1,3-bis(di-i-propylphosphino)propane
  • CAS Number: 91159-11-4
  • Molecular Formula: C15H34P2
  • Molecular Weight: 276.37800
  • Create Date: 2018-09-16 17:30:28
  • Modify Date: 2024-01-03 10:42:54

Name 1,3-bis(di-i-propylphosphino)propane
Synonyms bis-1,3-diisopropylphosphinopropane
Molecular Formula C15H34P2
Molecular Weight 276.37800
Exact Mass 276.21400
PSA 27.18000
LogP 5.97390

Section 1: Product Identification
Chemical Name:1,3-Bis(di-i-propylphosphino)propane, min. 98% (dippp)
CAS Registry Number:91159-11-4
Formula:(C3H7)2PCH2CH2CH2P(C3H7)2
EINECS Number:none
Chemical Family:organophosphine ligand
Synonym:1,3-Bis(di-2-propylphosphano)propane

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound91159-11-4100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Inhalation, skin, eyes
Eye Contact:Causes mild to moderate irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: Flammable. No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Remove sources of ignition. Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Store the material in a cool, dry place in a tightly sealed container. Handle and store under an inert
Handling and Storage:
atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:colorless to pale yellow liquid
Molecular Weight:276.38
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:prolonged exposure to air
Incompatibility:strong oxidizing agents, air, and halogens
Decomposition Products:carbon monoxide, carbon dioxide, phosphorous pentoxide, organic fumes

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to federal, state, and local regulations.

SECTION 14: Transportation
Shipping Name (CFR):Flammable liquids, N.O.S.
Hazard Class (CFR):3
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 1993
Shipping Name (IATA):Flammable liquid, N.O.S.
Hazard Class (IATA):3
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 1993

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Risk Phrases 11
Safety Phrases 16-26-36/37/39
RIDADR UN 1993

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91159-11-4 structure

91159-11-4

Literature: Lindner, Ekkehard; Schmid, Markus; Wald, Joachim; Queisser, Joachim A.; Gepraegs, Michael; Wegner, Peter; Nachtigal, Christiane Journal of Organometallic Chemistry, 2000 , vol. 602, # 1-2 p. 173 - 187

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91159-11-4 structure

91159-11-4

Literature: Tani, Kazuhide; Tanigawa, Eiji; Tatsuno, Yoshitaka; Otsuka, Sei Journal of Organometallic Chemistry, 1985 , vol. 279, p. 87 - 102