Name | dichloro(phenylsulfanylmethylidene)ruthenium,tricyclohexylphosphane |
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Synonyms |
Dichloro[(phenylsulfanyl)methylene]ruthenium - tricyclohexylphosphine (1:2)
Phosphine, tricyclohexyl-, compd. with dichloro[(phenylthio)methylene]ruthenium (2:1) |
Boiling Point | 383.4ºC at 760 mmHg |
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Molecular Formula | C43H72Cl2P2RuS |
Molecular Weight | 855.020 |
Flash Point | 195.6ºC |
Exact Mass | 854.325073 |
PSA | 52.48000 |
LogP | 16.39950 |
Vapour Pressure | 9.7E-06mmHg at 25°C |
Section 1: Product Identification Chemical Name:Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium (II) dichloride, min. 97% CAS Registry Number:219770-99-7 Formula:RuCl2(CHSC6H5)[P(C6H11)3]2 EINECS Number:none Chemical Family:metal-phosphine complexes Synonym:none
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound219770-99-7100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed. Primary Routes of Exposure:Inhalation, ingestion Eye Contact:Causes slight to mild irritation of the eyes Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep away from heat and Handling and Storage: direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective gloves. Ventilation:If possible, handle the material in an efficient fume hood. Respirator:No respirator required. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:purple pwdr. Molecular Weight:855.02 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:prolonged contact with air. Incompatibility:oxidizing agents, halogens and active metals carbon dioxide, carbon monoxide, organic fumes, phosphorous pentoxide, sulfur dioxide and ruthenium Decomposition Products: compounds SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
Risk Phrases | 36/37/38 |
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Safety Phrases | 26-36/37/39 |