151139-14-9

151139-14-9 structure
151139-14-9 structure

Name tris(2,2,6,6-tetramethyl-3,5-heptane-dionato)lanthanum tetraglyme adduct
Synonyms tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lanthanum(iii)tetraglyme adduct
tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lanthanum (iii) tetraglyme adduct (-la) (reo)
Boiling Point 125ºC 0,1mm
Melting Point 59ºC
Molecular Formula C43H79LaO11
Molecular Weight 910.98600
Exact Mass 910.46900
PSA 125.05000
LogP 9.36650

Section 1: Product Identification
Chemical Name:Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)lanthanum (III)tetraglyme adduct (99.9%-La) (REO)
CAS Registry Number:151139-14-9
Formula:La(C11H19O2)3.CH3(OCH2CH2)4OCH3
EINECS Number:none
Chemical Family:metal beta-diketonate complexes
Synonym:Dipivaloylmethane, lanthanum complex, tetraglyme adduct

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound151139-14-9100%no datano data

Section 3: Hazards Identification
Emergency Overview:May be irritating to eyes, skin and respiratory tract. Harmful if swallowed
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:May cause slight to mild irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:May cause irritation to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the effects of ingestion.
Acute Health Affects:May be irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
Inhalation:
breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothes and gloves. Consult glove manufacturer to determine the proper type of glove.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white to pale-yellow xtl.
Molecular Weight:688.72(911.00)
Melting Point:59°
Boiling Point:125°C /0.1mm
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, lanthanum salts and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data available
Mutagenic Effects:no data available
Tetratogenic Effects:no data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Risk Phrases 36/37/38
Safety Phrases 26-36/37/39