Name | 4-(4-bromophenyl)thiadiazole |
---|---|
Synonyms | MFCD00084907 |
Density | 1.642g/cm3 |
---|---|
Boiling Point | 341.5ºC at 760 mmHg |
Melting Point | 154ºC |
Molecular Formula | C8H5BrN2S |
Molecular Weight | 241.10800 |
Flash Point | 160.3ºC |
Exact Mass | 239.93600 |
PSA | 54.02000 |
LogP | 2.96760 |
Index of Refraction | 1.643 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 40753-13-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H5BrN2S Molecular Weight: 241.11 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen bromide, bromine. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 40753-13-7: XI3677500 LD50/LC50: Not available. Carcinogenicity: 4-(4-Bromophenyl)-1,2,3-thiadiazole - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 40753-13-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 40753-13-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 40753-13-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
Hazard Codes | Xi |
---|---|
Risk Phrases | R36/37/38 |
Safety Phrases | 26-36/37/39 |
HS Code | 2934999090 |
~94% 40753-13-7 |
Literature: Hu, Yonghan; Baudart, Sylvie; Porco Jr., John A. Journal of Organic Chemistry, 1999 , vol. 64, # 3 p. 1049 - 1051 |
~90% 40753-13-7 |
Literature: Kumar, Anil; Muthyala, Manoj Kumar; Choudhary, Sunita; Tiwari, Rakesh K.; Parang, Keykavous Journal of Organic Chemistry, 2012 , vol. 77, # 20 p. 9391 - 9396,6 |
~56% 40753-13-7 |
Literature: Hayat, Faisal; Salahuddin, Attar; Zargan, Jamil; Azam, Amir European Journal of Medicinal Chemistry, 2010 , vol. 45, # 12 p. 6127 - 6134 |
~% 40753-13-7 |
Literature: Hu, Yonghan; Baudart, Sylvie; Porco Jr., John A. Journal of Organic Chemistry, 1999 , vol. 64, # 3 p. 1049 - 1051 |
~% 40753-13-7 |
Literature: Ege,G. et al. Justus Liebigs Annalen der Chemie, 1977 , # 5 p. 791 - 799 |
~% 40753-13-7 |
Literature: Ege,G. et al. Justus Liebigs Annalen der Chemie, 1977 , # 5 p. 791 - 799 |
~% 40753-13-7 |
Literature: Ege,G. et al. Justus Liebigs Annalen der Chemie, 1977 , # 5 p. 791 - 799 |
~% 40753-13-7 |
Literature: Butler, Richard N.; O'Donoghue, Denis A. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , p. 1223 - 1228 |
Precursor 7 | |
---|---|
DownStream 0 |
HS Code | 2934999090 |
---|---|
Summary | 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |