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2439-99-8

2439-99-8 structure
2439-99-8 structure

Name glyphosine
Synonyms Glycine-N,N-bis(methylenephosphonic Acid)
N,N-di(phosphonomethyl) iminoacetic acid
N,N-bis(phosphonomethyl)aminoacetic acid
<<(carboxymethyl)imino>dimethylene>bisphosphonic acid
EINECS 219-468-4
Glyphosine [ANSI]
2-[bis(phosphonomethyl)amino]acetic acid
Glycine,N,N-bis(phosphonomethyl)
Glycine, N,N-bis(phosphonomethyl)-
N,N-bis-(phosphonomethyl)-glycine
Polaris
Glyphosphine
bis-phosphonomethyl glycine
MFCD00056670
2-(Bis(phosphonomethyl)amino)acetic acid
N,N-Bis(phosphonomethyl)glycine
nitriloacetatodimethylenephosphonic acid
N-Carboxymethyl-N,N-bis(methylenephosphonic Acid)amine
Caswell No. 471A
Glyphosine
Density 2.0±0.1 g/cm3
Boiling Point 668.4±65.0 °C at 760 mmHg
Melting Point 263°C
Molecular Formula C4H11NO8P2
Molecular Weight 263.080
Flash Point 358.0±34.3 °C
Exact Mass 262.996002
PSA 175.22000
LogP -2.89
Vapour Pressure 0.0±4.4 mmHg at 25°C
Index of Refraction 1.594

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MB9120000
CHEMICAL NAME :
Glycine, N,N-bis(phosphonomethyl)-
CAS REGISTRY NUMBER :
2439-99-8
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C4-H11-N-O8-P2
MOLECULAR WEIGHT :
263.10
WISWESSER LINE NOTATION :
QPQO&1N1VQ1PQQO

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3925 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 3,60,1976/1977 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1920 mg/kg/24D-C
TOXIC EFFECTS :
Liver - changes in liver weight Endocrine - changes in thymus weight Immunological Including Allergic - decrease in humoral immune response
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 30,103,1984
Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H318
Precautionary Statements P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R41
Safety Phrases S26-S2
RIDADR UN 3261 8/PG 3
WGK Germany 1
RTECS MB9120000
Packaging Group III
Hazard Class 8.0
HS Code 2931900042

~77%

2439-99-8 structure

2439-99-8

Literature: STRAITMARK HOLDING AG; NOTTE, Patrick; PIRARD, Cedric Nicolas; LEMIN, David Patent: WO2010/136566 A1, 2010 ; Location in patent: Page/Page column 15 ;

~85%

2439-99-8 structure

2439-99-8

Literature: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; INSTITUT NATIONAL DE LA SANTE ET DE LA RECHERCHE M; RHODIA UK LIMITED Patent: US2009/142316 A1, 2009 ; Location in patent: Page/Page column 116 ;

~92%

2439-99-8 structure

2439-99-8

Literature: Prishchenko, Andrey A.; Livantsov, Mikhail V.; Novikova, Olga P.; Livantsova, Ludmila I.; Petrosyan, Valery S. Heteroatom Chemistry, 2010 , vol. 21, # 6 p. 430 - 440

~61%

2439-99-8 structure

2439-99-8

Literature: Tsirul'nikova, N. V.; Temkina, V. Ya.; Sushitskaya, T. M.; Rykov, S. V. J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 5 p. 1028 - 1035,859 - 864

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2439-99-8

Detail
Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 58, # 10 p. 2238 - 2242,1992 - 1996

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2439-99-8 structure

2439-99-8

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 60, # 4.1 p. 734 - 737,639 - 641
HS Code 2931900042
Summary 2931900042 2-(bis(phosphonomethyl)amino)acetic acid。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%