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74724-75-7

74724-75-7 structure
74724-75-7 structure
  • Name: METHYLDIPHENYLBISMUTHINE
  • Chemical Name: methyl(diphenyl)bismuthane
  • CAS Number: 74724-75-7
  • Molecular Formula: C13H14Bi
  • Molecular Weight: 379.23100
  • Create Date: 2016-02-05 19:39:31
  • Modify Date: 2024-01-02 04:34:29

Name methyl(diphenyl)bismuthane
Synonyms methyldiphenylbismutane
Bismuthine,methyldiphenyl
methyldiphenylbismuthine
Methyldiphenylbismuth
Molecular Formula C13H14Bi
Molecular Weight 379.23100
Flash Point 92ºC
Exact Mass 379.09000
LogP 3.60970
Index of Refraction 1.6805-1.6825
Name: Diphenylmethylbismuthine Material Safety Data Sheet
Synonym:
CAS: 74724-75-7
Section 1 - Chemical Product MSDS Name:Diphenylmethylbismuthine Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
74724-75-7 Diphenylmethylbismuthine unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Air sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Combustible solid.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under an argon blanket.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 74724-75-7: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 92 deg C ( 197.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C13H13Bi
Molecular Weight: 378.075

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 74724-75-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Diphenylmethylbismuthine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 74724-75-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 74724-75-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 74724-75-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Safety Phrases S24/25
HS Code 2931900090

~72%

74724-75-7 structure

74724-75-7

Literature: Kauffmann, Thomas; Steinseifer, Fritz; Klas, Norbert Chemische Berichte, 1985 , vol. 118, # 3 p. 1039 - 1044

~70%

74724-75-7 structure

74724-75-7

Literature: Steinseifer, Fritz; Kauffmann, Thomas Angewandte Chemie, 1980 , vol. 92, # 9 p. 746 - 747

~89%

74724-75-7 structure

74724-75-7

Literature: Kauffmann, Thomas; Steinseifer, Fritz Chemische Berichte, 1985 , vol. 118, # 3 p. 1031 - 1038

~%

74724-75-7 structure

74724-75-7

Literature: Wieber, Markus; Sauer, Ingbert Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1984 , vol. 39, # 7 p. 887 - 889

~66%

74724-75-7 structure

74724-75-7

Literature: Althaus, Henrik; Breunig, Hans Joachim; Lork, Enno Organometallics, 2001 , vol. 20, # 3 p. 586 - 589
HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%