Pyrimidin-2,4,6-triamin

Modify Date: 2024-01-02 07:04:07

Pyrimidin-2,4,6-triamin Structure
Pyrimidin-2,4,6-triamin structure
Common Name Pyrimidin-2,4,6-triamin
CAS Number 1004-38-2 Molecular Weight 125.132
Density 1.5±0.1 g/cm3 Boiling Point 530.8±53.0 °C at 760 mmHg
Molecular Formula C4H7N5 Melting Point 249-251 °C(lit.)
MSDS Chinese USA Flash Point 308.2±18.1 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 2,4,6-triaminopyrimidine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 530.8±53.0 °C at 760 mmHg
Melting Point 249-251 °C(lit.)
Molecular Formula C4H7N5
Molecular Weight 125.132
Flash Point 308.2±18.1 °C
Exact Mass 125.070145
PSA 103.84000
LogP -1.01
Vapour Pressure 0.0±1.4 mmHg at 25°C
Index of Refraction 1.793
Water Solubility 36.5 g/L (20 ºC)

 MSDS

Name: 2 4 6-Triaminopyrimidine 97% Material Safety Data Sheet
Synonym:
CAS: 1004-38-2
Section 1 - Chemical Product MSDS Name:2 4 6-Triaminopyrimidine 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1004-38-2 2,4,6-Triaminopyrimidine, 97% 97% 213-720-7
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 1004-38-2: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: slightly beige
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 249 - 251 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble
Specific Gravity/Density:
Molecular Formula: C4H7N5
Molecular Weight: 125.13

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1004-38-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,4,6-Triaminopyrimidine, 97% - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 1004-38-2: No information available.
Canada
CAS# 1004-38-2 is listed on Canada's DSL List.
CAS# 1004-38-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1004-38-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant
Risk Phrases R36/37/38
Safety Phrases S26-S36-S37/39
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2933599090

 Synthetic Route

~%

Pyrimidin-2,4,6-triamin Structure

Pyrimidin-2,4,6...

CAS#:1004-38-2

Literature: Journal of the American Chemical Society, , vol. 72, p. 4271 Journal of the American Chemical Society, , vol. 73, p. 3862

~86%

Pyrimidin-2,4,6-triamin Structure

Pyrimidin-2,4,6...

CAS#:1004-38-2

Literature: Bioorganic and Medicinal Chemistry Letters, , vol. 15, # 1 p. 73 - 76

~%

Pyrimidin-2,4,6-triamin Structure

Pyrimidin-2,4,6...

CAS#:1004-38-2

Literature: Chemische Berichte, , vol. 37, p. 4547

~%

Pyrimidin-2,4,6-triamin Structure

Pyrimidin-2,4,6...

CAS#:1004-38-2

Literature: Chemische Berichte, , vol. 34, p. 3363

~%

Pyrimidin-2,4,6-triamin Structure

Pyrimidin-2,4,6...

CAS#:1004-38-2

Literature: Chemische Berichte, , vol. 36, p. 2234 Chemische Berichte, , vol. 34, p. 3363

~%

Pyrimidin-2,4,6-triamin Structure

Pyrimidin-2,4,6...

CAS#:1004-38-2

Literature: Journal of the American Chemical Society, , vol. 135, # 7 p. 2447 - 2450

~%

Pyrimidin-2,4,6-triamin Structure

Pyrimidin-2,4,6...

CAS#:1004-38-2

Literature: Chemische Berichte, , vol. 36, p. 2227 Chemische Berichte, , vol. 34, p. 3363

~82%

Pyrimidin-2,4,6-triamin Structure

Pyrimidin-2,4,6...

CAS#:1004-38-2

Literature: Australian Journal of Chemistry, , vol. 60, # 2 p. 120 - 123

~%

Pyrimidin-2,4,6-triamin Structure

Pyrimidin-2,4,6...

CAS#:1004-38-2

Literature: Journal of Heterocyclic Chemistry, , vol. 25, # 6 p. 1697 - 1700

 Customs

HS Code 2933599090
Summary 2933599090. other compounds containing a pyrimidine ring (whether or not hydrogenated) or piperazine ring in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles23

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Gen. Pharmacol. 18(6) , 589-92, (1987)

1. Values of the sodium potential (ENa), active conductance (GNa) and passive conductance (Gsh) were measured in the isolated skin of the toad Pleurodema thaul placed in an Ussing chamber, and Isaacso...

Mechanism of ammonium transport by intestinal segments following urinary diversion: evidence for ionized NH4+ transport via K(+)-pathways.

J. Urol. 148(2 Pt 1) , 453-7, (1992)

Using a previously reported in vivo intestinal perfusion model in the rat, we have shown that net total ammonium absorption accounts for the majority of the acid load resulting from urinary intestinal...

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Gut 31(1) , 64-9, (1990)

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 Synonyms

TRIAMINOPYRIMIDINE
EINECS 213-720-7
1,3,5-triaminopyrimidine
Pyrimidine-2,4,6-triamine
2,3-DIHYDRO-BENZOFURAN-3-YLAMINE HYDROCHLORIDE
6-TriaMinopyriMidine
2,4,6-Pyrimidinetriamine
MFCD00006100
2,4,6-triamino pyrimidine
2,4,6-Triaminopyrimidin
2,4,6-Triaminopyrimidene
IFLAB-BB F1918-0050
Pyrimidin-2,4,6-triamin
2,4,6-Traminopyrimidne
2,4,6-Triamino
2,4,6-Triaminopyrimidine
2,4,6-Triamino Pyridine
2,4,6-TRIAMINO-PYRIMIDINE
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