Benzyl formate

Modify Date: 2024-01-02 19:18:31

Benzyl formate Structure
Benzyl formate structure
 Common Name Benzyl formate
CAS Number 104-57-4 Molecular Weight 136.148
Density 1.1±0.1 g/cm3 Boiling Point 203.8±9.0 °C at 760 mmHg
Molecular Formula C8H8O2 Melting Point 4ºC
MSDS Chinese USA Flash Point 99.5±9.3 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name Benzyl formate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 203.8±9.0 °C at 760 mmHg
Melting Point 4ºC
Molecular Formula C8H8O2
Molecular Weight 136.148
Flash Point 99.5±9.3 °C
Exact Mass 136.052429
PSA 26.30000
LogP 1.54
Vapour Pressure 0.3±0.4 mmHg at 25°C
Index of Refraction 1.511

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ5400000
CHEMICAL NAME :
Formic acid, benzyl ester
CAS REGISTRY NUMBER :
104-57-4
BEILSTEIN REFERENCE NO. :
2041319
LAST UPDATED :
199709
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C8-H8-O2
MOLECULAR WEIGHT :
136.16
WISWESSER LINE NOTATION :
VHO1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
DNA repair
TEST SYSTEM :
Bacteria - Bacillus subtilis
DOSE/DURATION :
22 mg/disc
REFERENCE :
OIGZDE Osaka-shi Igakkai Zasshi. Journal of Osaka City Medical Association. (Osaka-shi Igakkai, c/o Osaka-shiritsu Daigaku Igakubu, 1-4-54 Asahi-cho, Abeno-ku, Osaka, 545, Japan) V.24- 1975- Volume(issue)/page/year: 34,267,1985 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0379 No. of Facilities: 259 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 7246 (estimated) No. of Female Employees: 6082 (estimated)

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302 + H312
Precautionary Statements P280
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn
Risk Phrases R21/22
Safety Phrases S36-S36/37
RIDADR NA 1993 / PGIII
WGK Germany 1
RTECS LQ5400000
HS Code 2915120000

 Synthetic Route

 Customs

HS Code 2915120000
Summary 2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

 Synonyms

benzyloxycarbonyl
EINECS 203-214-4
Formic acid,benzyl ester
Ameisensaeure-benzylester
Formic acid phenylmethyl ester
MFCD00014128
Formic acid,phenylmethyl ester
Benzyl formiat
Benzyl alcohol,formate
benzylformate
Formic acid, benzyl ester
Formic acid, phenylmethyl ester
phenylmethyl ester of formic acid,benzyl formic ester
Benzyl formate
formic acid benzyl ester
Phenylmethyl formate
Benzyl alcohol, formate
Benzyl methanoate
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