3-Mesityl-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate
![3-Mesityl-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate Structure](https://image.chemsrc.com/caspic/419/1062158-63-7.png)
3-Mesityl-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate structure
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Common Name | 3-Mesityl-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate | ||
|---|---|---|---|---|
| CAS Number | 1062158-63-7 | Molecular Weight | 371.87900 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C17H22ClNO4S | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | 3-(2,4,6-trimethylphenyl)-5,6,7,8-tetrahydro-4H-cyclohepta[d][1,3]thiazol-3-ium,perchlorate |
|---|---|
| Synonym | More Synonyms |
| Molecular Formula | C17H22ClNO4S |
|---|---|
| Molecular Weight | 371.87900 |
| Exact Mass | 371.09600 |
| PSA | 106.39000 |
| LogP | 4.43320 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Hazard Codes | Xi |
| RIDADR | NONH for all modes of transport |
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3-Mesityl-5,6,7... CAS#:1062158-63-7 |
| Literature: Lebeuf, Raphael; Hirano, Keiichi; Glorius, Frank Organic Letters, 2008 , vol. 10, # 19 p. 4243 - 4246 |
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3-Mesityl-5,6,7... CAS#:1062158-63-7 |
| Literature: Piel, Isabel; Pawelczyk, Marius D.; Hirano, Keiichi; Froehlich, Roland; Glorius, Frank European Journal of Organic Chemistry, 2011 , # 28 p. 5475 - 5484 |
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3-Mesityl-5,6,7... CAS#:1062158-63-7 |
| Literature: Piel, Isabel; Pawelczyk, Marius D.; Hirano, Keiichi; Froehlich, Roland; Glorius, Frank European Journal of Organic Chemistry, 2011 , # 28 p. 5475 - 5484 |
![3-mesityl-3,4,5,6,7,8-hexahydro-2H-cyclohepta[d]thiazole-2-thione structure](https://image.chemsrc.com/caspic/495/1062158-61-5.png)
| Precursor 3 | |
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| DownStream 0 | |
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Palladium-catalyzed C-allylation of benzoins and an NHC-catalyzed three component coupling derived thereof: compatibility of NHC- and Pd-catalysts.
Org. Lett. 10 , 4243-4246, (2008) A large range of benzoins was successfully applied as C-nucleophiles in the palladium-catalyzed allylic alkylation with several allyl acetates, resulting in functionalized tertiary homoallylic alcohol... |
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N-heterocyclic carbene-catalyzed hydroacylation of unactivated double bonds.
J. Am. Chem. Soc. 131 , 14190-14190, (2009) An intramolecular N-heterocyclic carbene (NHC)-catalyzed hydroacylation of unactivated double bonds is reported. Systematic variation of the catalyst structure revealed an N-mesitylthiazolylidene annu... |
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N-heterocyclic carbene-catalyzed cascade reaction involving the hydroacylation of unactivated alkynes.
J. Am. Chem. Soc. 132 , 5970-5971, (2010) The N-heterocyclic carbene (NHC)-catalyzed hydroacylation of unactivated alkynes to provide alpha,beta-unsaturated ketones is reported. In addition, a rare case of an efficient and selective dually NH... |
| 3-(2,4,6-Trimethylphenyl)-5,6,7,8-tetrahydro-4H-cycloheptathiazol-3-ium perchlorate |
| Isa-Carbene |
| Isa-NHC |