2-Pipecoline

Modify Date: 2024-01-09 19:49:10

2-Pipecoline Structure
2-Pipecoline structure
Common Name 2-Pipecoline
CAS Number 109-05-7 Molecular Weight 99.174
Density 0.8±0.1 g/cm3 Boiling Point 118.8±0.0 °C at 760 mmHg
Molecular Formula C6H13N Melting Point -4--5 °C
MSDS Chinese USA Flash Point 8.3±0.0 °C
Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger

 Names

Name 2-Methylpiperidine
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.8±0.1 g/cm3
Boiling Point 118.8±0.0 °C at 760 mmHg
Melting Point -4--5 °C
Molecular Formula C6H13N
Molecular Weight 99.174
Flash Point 8.3±0.0 °C
Exact Mass 99.104797
PSA 12.03000
LogP 1.42
Vapour Pressure 16.4±0.2 mmHg at 25°C
Index of Refraction 1.422
Storage condition Flammables area
Water Solubility soluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TN1240000
CHEMICAL NAME :
Piperidine, 2-methyl-
CAS REGISTRY NUMBER :
109-05-7
BEILSTEIN REFERENCE NO. :
0079804
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C6-H13-N
MOLECULAR WEIGHT :
99.20
WISWESSER LINE NOTATION :
T6MTJ B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
300 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
BDCGAS Berichte der Deutschen Chemischen Gesellschaft. (Leipzig, Ger. Dem. Rep.) V.1-61, 1868-1928. For publisher information, see CHBEAM. Volume(issue)/page/year: 34,2408,1901 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84360 No. of Facilities: 5 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 20 (estimated)

 Safety Information

Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger
Hazard Statements H225-H302-H315-H318-H335
Precautionary Statements P210-P261-P280-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable;Xn:Harmful;
Risk Phrases R11;R22;R34
Safety Phrases S16-S26-S39-S45-S36/37/39
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS TN1240000
Packaging Group II
Hazard Class 3
HS Code 29333999

 Synthetic Route

 Customs

HS Code 2933399090
Summary 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles12

More Articles
C-2 arylation of piperidines through directed transition-metal-catalyzed sp3 C-H activation.

Chemistry 16 , 13063-13067, (2010)

Gold-catalyzed efficient synthesis of azepan-4-ones via a two-step [5 + 2] annulation.

Chem. Commun. (Camb.) 46 , 3351-3353, (2010)

A surprisingly efficient synthesis of azepan-4-ones via a two-step [5 + 2] annulation is developed. This reaction involves a key gold catalysis and shows generally high regioselectivities and good to ...

Acetoacetanilides as masked isocyanates: facile and efficient synthesis of unsymmetrically substituted ureas.

Org. Lett. 12 , 4220-4223, (2010)

A general and practical method for the preparation of unsymmetrically substituted ureas has been developed. By the reactions of acetoacetanilides with various amines including primary/secondary amines...

 Synonyms

Piperidine,2-methyl
2-METHYLPIPERIDIN
α-Pipecolin
Pipicoline
2-Pipecoline
EINECS 203-642-1
2-Pipecoline (8CI)
Piperidine, 2-methyl-
2-METHYL PIPERIDINE
2-METHYL-PIPERIDINE
2-METHYLPIPERIDINE FOR SYNTHESIS
2-METHYLPIPERIDINE/2-PIPECOLINE
2-Methylpiperidine
α-Pipecoline
MFCD00005982
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