bis(2-Chloroethoxy)methane

Modify Date: 2024-01-03 20:01:21

bis(2-Chloroethoxy)methane Structure
bis(2-Chloroethoxy)methane structure
 Common Name bis(2-Chloroethoxy)methane
CAS Number 111-91-1 Molecular Weight 173.03800
Density 1.18g/cm3 Boiling Point 112°C/20mm
Molecular Formula C5H10Cl2O2 Melting Point -32.3°C
MSDS USA Flash Point 76.9ºC

 Names

Name bis(2-Chloroethoxy)methane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.18g/cm3
Boiling Point 112°C/20mm
Melting Point -32.3°C
Molecular Formula C5H10Cl2O2
Molecular Weight 173.03800
Flash Point 76.9ºC
Exact Mass 172.00600
PSA 18.46000
LogP 1.45470
Vapour Pressure 0.35mmHg at 25°C
Index of Refraction 1.437

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
PA3675000
CHEMICAL NAME :
Methane, bis(2-chloroethoxy)-
CAS REGISTRY NUMBER :
111-91-1
BEILSTEIN REFERENCE NO. :
1698909
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C5-H10-Cl2-O2
MOLECULAR WEIGHT :
173.05
WISWESSER LINE NOTATION :
G2O1O2G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 30,63,1948
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
AJOPAA American Journal of Ophthalmology. (Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611) Series 3: V.1- 1918- Volume(issue)/page/year: 29,1363,1946 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
65 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 30,63,1948
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
62 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,343,1949
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
170 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 30,63,1948

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases 25
Safety Phrases 45
RIDADR 2810
Packaging Group III
Hazard Class 6.1(b)
HS Code 2909199090

 Synthetic Route

trioxane structure

trioxane

CAS#:110-88-3

2-Chloroethanol structure

2-Chloroethanol

CAS#:107-07-3

~0%

bis(2-Chloroethoxy)methane Structure

bis(2-Chloroeth...

CAS#:111-91-1

2-Chloroethyl Chloromethyl Ether structure

2-Chloroethyl C...

CAS#:1462-33-5

Literature: Journal of Heterocyclic Chemistry, , vol. 37, # 5 p. 1187 - 1191
Formaldehyde structure

Formaldehyde

CAS#:50-00-0

2-Chloroethanol structure

2-Chloroethanol

CAS#:107-07-3

~%

bis(2-Chloroethoxy)methane Structure

bis(2-Chloroeth...

CAS#:111-91-1

Literature: Journal of the Chemical Society, , p. 806,808
ETHYLENE OXIDE structure

ETHYLENE OXIDE

CAS#:75-21-8

2-Chloroethyl Chloromethyl Ether structure

2-Chloroethyl C...

CAS#:1462-33-5

~%

bis(2-Chloroethoxy)methane Structure

bis(2-Chloroeth...

CAS#:111-91-1

Literature: Justus Liebigs Annalen der Chemie, , vol. 710, p. 59 - 70
Formaldehyde structure

Formaldehyde

CAS#:50-00-0

Ethane,1,1',1''-[methylidynetris(oxy)]tris[2-chloro- structure

Ethane,1,1',1''...

CAS#:18719-58-9

2-Chloroethanol structure

2-Chloroethanol

CAS#:107-07-3

~%

bis(2-Chloroethoxy)methane Structure

bis(2-Chloroeth...

CAS#:111-91-1

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 92, p. 1027 - 1039
(1-chloro-ethyl)-chloromethyl ether structure

(1-chloro-ethyl...

CAS#:186318-82-1

2-Chloroethanol structure

2-Chloroethanol

CAS#:107-07-3

~%

bis(2-Chloroethoxy)methane Structure

bis(2-Chloroeth...

CAS#:111-91-1

Literature: Bulletin de la Societe Chimique de France, , vol. <3>13, p. 592 Chemische Berichte, 28 Ref. <1895>,851
2-Chloroethyl Chloromethyl Ether structure

2-Chloroethyl C...

CAS#:1462-33-5

2-Chloroethanol structure

2-Chloroethanol

CAS#:107-07-3

~%

bis(2-Chloroethoxy)methane Structure

bis(2-Chloroeth...

CAS#:111-91-1

Literature: Bulletin de la Societe Chimique de France, , vol. <4>3, p. 256

 Customs

HS Code 2909199090
Summary 2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

 Synonyms

1-chloro-2-(2-chloroethoxymethoxy)ethane
MFCD00045293
EINECS 203-920-2
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