Benzene,1-(3-bromopropoxy)-4-fluoro- structure
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Common Name | Benzene,1-(3-bromopropoxy)-4-fluoro- | ||
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CAS Number | 1129-78-8 | Molecular Weight | 233.07800 | |
Density | 1.422g/cm3 | Boiling Point | 282.7ºC at 760mmHg | |
Molecular Formula | C9H10BrFO | Melting Point | N/A | |
MSDS | N/A | Flash Point | 148.8ºC |
Name | 1-(3-bromopropoxy)-4-fluorobenzene |
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Synonym | More Synonyms |
Density | 1.422g/cm3 |
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Boiling Point | 282.7ºC at 760mmHg |
Molecular Formula | C9H10BrFO |
Molecular Weight | 233.07800 |
Flash Point | 148.8ºC |
Exact Mass | 231.99000 |
PSA | 9.23000 |
LogP | 2.98950 |
Vapour Pressure | 0.00564mmHg at 25°C |
Index of Refraction | 1.521 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Lachrymator (substance which increases the flow of tears). Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1129-78-8: Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 155 deg C @12mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: >200 deg C Solubility in water: Specific Gravity/Density: Molecular Formula: C9H10BrFO Molecular Weight: 233.08 Section 10 - STABILITY AND REACTIVITY Chemical Stability: No information found. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen bromide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1129-78-8 unlisted. LD50/LC50: Not available. Carcinogenicity: 1-(3-Bromopropoxy)-4-fluorobenzene - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing Group: III IMO Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing Group: III RID/ADR Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2810 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/22 Harmful by inhalation and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 1129-78-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 1129-78-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1129-78-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xn: Harmful;Xi: Irritant; |
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Risk Phrases | R36/37/38 |
Safety Phrases | S37/39 |
HS Code | 2909309090 |
~83% Benzene,1-(3-br... CAS#:1129-78-8 |
Literature: Jensen; Ager; Bliss; Canfield; Kotecka; Rieckmann; Terpinski; Jacobus Journal of Medicinal Chemistry, 2001 , vol. 44, # 23 p. 3925 - 3931 |
~73% Benzene,1-(3-br... CAS#:1129-78-8 |
Literature: Eisai Co., Ltd. Patent: US2002/19531 A1, 2002 ; US 20020019531 A1 |
~% Benzene,1-(3-br... CAS#:1129-78-8 |
Literature: Journal of Medicinal Chemistry, , vol. 8, p. 62 - 73 |
HS Code | 2909309090 |
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Summary | 2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0% |
3-(4-fluorophenoxy)propyl bromide |
1-bromo-3-(4-fluorophenoxy)propane |
1-(3-bromopropyloxy)-4-fluorobenzene |
1-(3'-bromopropoxy)-4-fluorobenzene |
1-(4'-fluorophenoxy)-3-bromopropane |
1-bromo-3-(p-fluorophenoxy)propane |