3,3-Pentamethylene glutarimide

Modify Date: 2024-01-02 09:20:57

3,3-Pentamethylene glutarimide Structure
3,3-Pentamethylene glutarimide structure
Common Name 3,3-Pentamethylene glutarimide
CAS Number 1130-32-1 Molecular Weight 181.232
Density 1.1±0.1 g/cm3 Boiling Point 362.3±11.0 °C at 760 mmHg
Molecular Formula C10H15NO2 Melting Point 84-89 °C(lit.)
MSDS N/A Flash Point 161.2±19.4 °C

 Names

Name 3,3-Pentamethylene Glutarimide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 362.3±11.0 °C at 760 mmHg
Melting Point 84-89 °C(lit.)
Molecular Formula C10H15NO2
Molecular Weight 181.232
Flash Point 161.2±19.4 °C
Exact Mass 181.110275
PSA 46.17000
LogP 2.04
Vapour Pressure 0.0±0.8 mmHg at 25°C
Index of Refraction 1.518
Storage condition Refrigerator

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: 3,3-Pentamethylene glutarimide
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.

Section3. Composition/information on ingredients.
Ingredient name:3,3-Pentamethylene glutarimide
CAS number:1130-32-1

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels.
Storage:

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
No data
Melting point:
Flash point:No data
Density:No data
Molecular formula:C10H15NO2
Molecular weight:181.2

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
Non-harzardous for air and ground transportation.

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CM0215000
CHEMICAL NAME :
3-Azaspiro(5,5)undecan-2,4-dione
CAS REGISTRY NUMBER :
1130-32-1
BEILSTEIN REFERENCE NO. :
0383782
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C10-H15-N-O2
MOLECULAR WEIGHT :
181.26
WISWESSER LINE NOTATION :
T6VMV EXTJ E-& AL6XTJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
REFERENCE :
ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 10,243,1960
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
17200 ug/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
REFERENCE :
FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2- 1939- Volume(issue)/page/year: 27,278,1964

 Safety Information

Hazard Codes T+
Safety Phrases S22-S24/25
WGK Germany 3
RTECS CM0120000
HS Code 2925190090

 Synthetic Route

~96%

3,3-Pentamethylene glutarimide Structure

3,3-Pentamethyl...

CAS#:1130-32-1

Literature: Divi, Murali Krishna Prasad; Rao, Bandarupalli Leela Maheswara; Rao, Aswatha Narayana Organic Preparations and Procedures International, 2013 , vol. 45, # 6 p. 504 - 506

~98%

3,3-Pentamethylene glutarimide Structure

3,3-Pentamethyl...

CAS#:1130-32-1

Literature: Erregierre, S.p.A. Patent: WO2004/31126 A2, 2004 ; Location in patent: Page 3 ;

~%

3,3-Pentamethylene glutarimide Structure

3,3-Pentamethyl...

CAS#:1130-32-1

Literature: WO2005/90310 A2, ; Page/Page column 8 ;

 Customs

HS Code 2925190090
Summary 2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Synonyms

MFCD00177938
EINECS 214-459-1
3,3-Pentamethylene glutarimide
3-Azaspiro[5.5]undecane-2,4-dione
3,3-PENTAMETHYLENEGLUTARIMIDE
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